17102-85-1

Upstream product

• 55-21-0 benzamide 
• 123-11-5 4-methoxy-benzaldehyde 
• 288-32-4 1H-imidazole 
• 60-35-5 acetamide 
• 105-13-5 4-Methoxybenzyl alcohol 
• 100-47-0 benzonitrile 
• 825-60-5 benzimidic acid ethyl ester 
• 25408-75-7 N,N'-dibenzoylsulfur diimide 
• 40891-01-8 4-(dimorpholinomethyl)-1-methoxybenzene 

Downstream Products

• 10374-25-1 N-benzoyl-1-methoxy-1-(p-methoxyphenyl)-methylamine 

Relevant academic research and scientific papers

Surface modified novel magnetically tuned halloysite functionalized sulfonic acid: synthesis, characterization and catalytic activity

This work presents preparation of a surface modified magnetically tuned solid acid where thiol groups were grafted on magnetic halloysite, followed by oxidation of thiol groups to sulfonic acid groups. The physicochemical properties of the catalyst were a

Synthesis and characterization of a novel organic–inorganic hybrid salt and its application as a highly effectual Br?nsted–Lewis acidic catalyst for the production of N,N′-alkylidene bisamides

In this research, a novel organic–inorganic hybrid salt, namely, N1,N1,N2,N2-tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium tetrachloroferrate ([TMBSED][FeCl4]2) was

Graphene oxide anchored with sulfonic acid-functionalized glycerin: production, characterization and catalytic performance for the synthesis of N,N′-alkylidene bisamides

Abstract: A novel nanosheet-structured material, namely graphene oxide anchored with sulfonic acid-functionalized glycerin (GO@Gl-SO3H), was prepared and characterized by FTIR, EDS, FESEM, TEM and XRD analyses. Afterward, its catalytic performa

Benzimidates as gem-Diamidation and Amidoindolyzation Cascade Synthons with a Hydrated NiII Catalyst

We contributed a new benzimidate chemistry through moisture-insensitive NiII/NiII-FeIII combo-catalysis for a simultaneous 2-3 bond-forming gem-diamidation and amidoindolyzation cascade reaction to construct symmetrical an

The synthesis and structure of pyridine-oxadiazole iridium complexes and catalytic applications: Non-coordinating-anion-tuned selective C–N bond formation

Several novel pyridine-oxadiazole iridium complexes were synthesized and characterized through X-ray crystallography. The designed iridium complexes revealed surprisingly high catalytic activity in C–N bondformation of amides and benzyl alcohols with the assistance of non-coordinating anions. In an attempt to achieve borrowing hydrogen reactions of amides with benzyl alcohols, N,N'-(phenylmethylene)dibenzamide products were unexpectedly isolated under non-coordinating anion conditions, whereas N-benzylbenzamide products were achieved in the absence of non-coordinating anions. The mechanism explorations excluded the possibility of “silver effect” (silver-assisted or bimetallic catalysis) and revealed that the reactivity of iridium catalyst was varied by non-coordinating anions. This work provided a convenient and useful methodology that allowed the iridium complex to be a chemoselective catalyst and demonstrated the first example of non-coordinating-anion-tuned selective C–N bond formation

N,N,N′,N′-tetramethylethylene-diaminium-N,N′-disulfonic acid trifluoroacetate and pyridinium-N-sulfonic acid hydrogen sulfate as highly effective dual-functional catalysts for the preparation of N,N′-alkylidene bisamides

In this research, Br?nsted-acidic ionic liquids N,N,N′,N′-tetramethylethylene-diaminium-N,N′-disulfonic acid trifluoroacetate ([TMEDSA][TFA]2) and pyridinium-N-sulfonic acid hydrogen sulfate ([Py-SO3H][HSO4]) have been introduced as dual-functional catalysts for the green, simple and effective preparation of N,N′-alkylidene bisamides by the reaction of primary amides (2 eq.) with arylaldehydes (1 eq.) under solvent-free conditions. The reaction results and conditions of the catalysts have been compared with the previously reported ones. [TMEDSA][TFA]2 and [Py-SO3H][HSO4] were superior to the previously reported catalysts in terms of two or more of these factors: Reaction times (10-45 min), yields (86-98%), temperature and the reaction conditions. Additionally, a plausible and attractive mechanism based on dual functionality of the catalysts has been proposed.

Gold nanoparticles deposited on MnO2 nanorods modified graphene oxide composite: A potential ternary nanocatalyst for efficient synthesis of betti bases and bisamides

The decoration of novel nanostructures such as nano particle and nanorod on the surface of graphene oxide (GO) generate potential heterogeneous nanocatalyst. Highlighting this, in the present work, we have designed a ternary GO-MnO2-Au nanocomposite by decorating MnO2nanorods on the surface of graphene oxide via hydrothermal method, followed by deposition of Au nanoparticles on GO-MnO2 surface. The prepared nanocomposite was thoroughly characterised by different instrumental techniques such as X-Ray diffraction (XRD),Fourier transform infrared spectroscopy (FTIR),Raman spectroscopy, Field emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), High resolution Transmission electron microscopy (HRTEM), X-Ray photo electron spectroscopy (XPS), N2 adsorption desorption Brunauer–Emmett–Teller (BET) isotherm and Inductively coupled plasma - optical emission spectrometry (ICP-OES). FESEM and TEM images demonstrated that the MnO2 forms rod like structure having diameter of 60–100 nm and are uniformly distributed over the GO surface. HRTEM image clearly signifies gold (Au) nanoparticles having diameter of 7 ± 1.9 nm homogeneously distributed throughout the GO-MnO2 surface. Elementary state of Au and tetravalent nature of Mn as well as reduction of functional group after the decoration was confirmed from XPS studies. The catalyst GO-MnO2-Au was found to be the superior catalyst for synthesis of biologically active molecules such as Betti bases and Bisamides. The high catalytic activity of the materials can be attributed to the small and homogeneous distribution of gold nanoparticles, high redox potential of rod shaped MnO2 and the synergistic effect between GO, MnO2 and Au. All the reaction conditions were optimised by varying catalyst dosage, effect of solvent and temperature. The GO-MnO2-Au was easily recycled with minimal leaching and the product yield was found to be 85–90% after 4th cycle demonstrating the stability and durability of our nanocomposite.

Carbon-based nanocatalyst:?An efficient and recyclable heterogeneous catalyst for one-pot synthesis of gem-bisamides, hexahydroacridine-1,8-diones and 1,8-dioxo-octahydroxanthenes

Abstract: In this abstract, we discuss the progress related to sulfonated carbon-based materials in various acid-catalyzed organic transformations which are then further utilized in medicinal field, laboratories and industries. A simple and novel methodol

Immobilization of dihydrogen phosphate onto rice husk ash as a highly efficient and green catalyst for the synthesis of symmetrical N,N′-alkylidene bisamides

The preparation and characterization of an environmentally-benign and low-cost catalyst consisting of KH2PO4 supported on silica from rice husk ash is reported. The prepared catalyst was characterized by FT-IR spectroscopy, field emi

A nano silver-xerogel (Ag nps@modified TEOS) as a newly developed nanocatalyst in the synthesis of benzopyranopyrimidines (with secondary and primary amines) and: Gem -bisamides

Silver nanoparticles have been prepared from a chemical reduction approach and supported on modified TEOS (tetraethylorthosilicate) xerogels to be studied as a nanocatalyst in the conversions of benzopyranopyrimidines (with primary as well as secondary am