1712-82-9

Basic information

• Product Name: Peroxide, bis(4-bromobenzoyl)
• CAS NO: 1712-82-9
• Molecular Formula: C14H8Br2O4
• Molecular Weight: 400.023
• Mol File: 1712-82-9.mol

Chemical Properties

• CAS DataBase Reference: Peroxide, bis(4-bromobenzoyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, bis(4-bromobenzoyl)(1712-82-9)
• EPA Substance Registry System: Peroxide, bis(4-bromobenzoyl)(1712-82-9)

Safety Data

• Hazardous Substances Data: 1712-82-9(Hazardous Substances Data)

Upstream product

• 586-75-4 4-chlorobenzoyl chloride 
• 586-76-5 4-Bromobenzoic acid 

Downstream Products

• 66047-74-3 4-(4-bromophenyl)-2-methyl-1,3-thiazole 
• 82726-29-2 5-(4-bromo-phenyl)-2-methyl-thiazole 
• 127563-58-0 6-(4′-bromophenyl)phenanthridine 
• 1255772-46-3 3-(4-bromophenyl)-1-methylquinoxalin-2(1H)-one 
• 59635-31-3 2-(4-bromophenyl)-5-phenyl-2H-tetrazole 
• 1266356-00-6 3-(1-octen)-yl 4-bromobenzoate 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 42498-38-4 N-(tert-butyl)-4-bromobenzamide 
• 1174895-51-2 2-(4'-bromo-[1,1'-biphenyl]-2-yl)pyridine 

Relevant articles and documents

Aryl acyl peroxides for visible-light induced decarboxylative arylation of quinoxalin-2(1: H)-ones under additive-, metal catalyst-, and external photosensitizer-free and ambient conditions

Aryl radicals were generated for the first time from cheap and easily available aryl acyl peroxides in eco-friendly ethyl acetate under ambient conditions and visible-light illumination in the absence of any additive, metal catalyst, or external photosensitizer. The present arylation of quinoxalin-2(1H)-ones was chemo- and regioselective, and provided good access to various 3-arylquinoxalin-2(1H)-ones. This journal is

Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives

Oxygenative cleavage of an inert CAr-NH2 bond with concomitant 1,2 amine migration in 8-aminoquinoline derivatives is reported in water at room temperature. The reaction is highly atom- and step-economical as both C- and N-containing fragments of the C-N bond cleavage are incorporated into the target molecule and is effected without the need for N-oxide. The reaction is scalable to gram level, and the products are useful as electrophilic partners for coupling reactions, ligands in catalysis and bioactive compounds.

A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

An efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. A variety of anilides reacted with aryl acylperoxides to afford the corresponding ortho-arylation products, and N-methoxyarylamides generated phenanthridinones. This journal is

Palladium(II)-catalyzed othro-C-H-benzoxylation of 2-arylpyridines by oxidative coupling with aryl acylperoxides

A palladium(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with aryl acylperoxides was developed. With pyridyl as directing group, the benzoxylation reaction exhibits remarkable regioselectivity and excellent functional group tolerance, providing the products in up to 87% yield.

Palladium-catalyzed decarboxylative arylation of C-H bonds by aryl acylperoxides

A Pd(OAc)2-catalyzed protocol for decarboxylative arylation of aromatic C-H bond was developed using aryl acylperoxides as inexpensive aryl sources. Substrates containing pyridyl, oxime, and oxazoline groups undergo effectively ortho-selective C-H arylation with excellent functional group tolerance. This arylation should begin by directing-group-assisted cyclopalladation, followed by the reaction of the palladacycle with aryl radicals generated in situ by thermal decomposition of the peroxides.