17141-01-4

Basic information

• Product Name: {Ru(CO)2Cl₂(P(C₆H₅)(CH₃)2)2}
• CAS NO: 17141-01-4
• Molecular Weight: 504.295
• Mol File: 17141-01-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: {Ru(CO)2Cl₂(P(C₆H₅)(CH₃)2)2}(CAS DataBase Reference)
• NIST Chemistry Reference: {Ru(CO)2Cl₂(P(C₆H₅)(CH₃)2)2}(17141-01-4)
• EPA Substance Registry System: {Ru(CO)2Cl₂(P(C₆H₅)(CH₃)2)2}(17141-01-4)

Safety Data

• Hazardous Substances Data: 17141-01-4(Hazardous Substances Data)

Upstream product

• 14898-67-0 ruthenium(III) chloride trihydrate 
• 672-66-2 Dimethyl(phenyl)phosphine 
• 201230-82-2 carbon monoxide 
• 17141-01-4 all-trans-[Ru(CO)2(PMe₂Ph)Cl₂] 
• 593-74-8 dimethylmercury 
• 112287-52-2 [Ru(CO)2(H)2(P(CH₃)2C₆H₅)2] 
• 17141-01-4 cct-(PhMe₂P)2Ru(II)(CO)2Cl₂ 

Downstream Products

• 17141-01-4 cct-(PhMe₂P)2Ru(II)(CO)2Cl₂ 
• 17141-01-4 all-trans-[Ru(CO)2(PMe₂Ph)Cl₂] 
• 60660-63-1 cis-{RuBr₂(CO)2(C₈H₁₁P)2} 
• 60660-64-2 cis-{RuI₂(CO)2(C₈H₁₁P)2} 
• 112287-56-6 Ru(CO)2Cl(H)(P(CH₃)2(C₆H₅))2 
• 112287-52-2 [Ru(CO)2(H)2(P(CH₃)2C₆H₅)2] 
• 60595-73-5 [Ru(CO)(η-C2H4)Cl2(PMe2Ph)2] 
• 60663-27-6 [(Ru(CO)Cl₂(P(CH₃)2C₆H₅)2)2] 
• 60663-27-6 [Ru₂(CO)2Cl₄(P(CH₃)2C₆H₅)4] 
• 60595-70-2 Ru(CO)(P(CH₃)2C₆H₅)2(NCC₆H₅)Cl₂ 
• 60595-69-9 Ru(CO)(P(CH₃)2C₆H₅)2(NCCH₃)Cl₂ 
• 60584-07-8 Ru(CO)(P(CH₃)2C₆H₅)2(C₅H₅N)Cl₂ 
• 60584-08-9 Ru(CO)(P(CH₃)2C₆H₅)2(NH₃)Cl₂ 
• 60584-11-4 Ru(CO)Cl₂(P(CH₃)2C₆H₅)2(P(C₆H₅)(OCH₃)2) 

Relevant articles and documents

Intramolecular combination of vinyl, aryl and carbonyl ligands in ruthenium(II) complexes: a mechanistic study

Complexes underwent competing isomerisation reactions, one an intramolecular construction of a vinyl aryl ketone which remains co-ordinated, the other a simple redistribution of the ligands around the metal.Product ratios are determined by kinetic rather than thermodynamic factors.For a sequence of complexes with L = L' = PMe2Ph, electron-releasing substituents on the vinyl ligand favour formation of ketone complexes, whereas similar substituents on the phenyl ligand have the reverse effect.Increasing the reaction temperature disfavours ketone complex formation.Mechanisms involving initial migration of either the vinyl or the aryl ligand are discussed on the basis of these results and a complementary study involving trapping of the likely acyl intermediates.

Solid-phase thermal isomerization of (R3P)2Ru(CO)2Cl2 and (R3P)3Ru(CO)Cl2 complexes

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Preparation, Isomerization, and Reactions of Hydride Complexes of Ruthenium(II)

Hydride complexes 2> (X = H or Cl, L = PMe2Ph or AsMe2Ph) and their deuteride analogues have been prepared.The complex exists in solution as an equilibrium mixture of isomers.The dideuteride exchanges with H2 in solution: no is formed, suggesting that exchange occurs via .Exchange also occurs with ethene and propene: here is observed.Ethene is hydrogenated by 2>, with formation of ethane and complexes 2>, which are reconverted to 2> by H2.The terminal alkenes 1-hexene and 3-phenylpropene are isomerized by 2>: for L = AsMe2Ph, a little hydrogenation of 3-phenylpropene also occurs.