17219-58-8Relevant articles and documents
Efficient cis-to-trans isomerization of 1,4-dihalobutene-2
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, (2008/06/13)
This invention relates to an efficient cis-to-trans isomerization of 1,4-dihalobutene-2 by means of a thiol or hydrogen bromide or hydrogen chloride catalyzed reaction.
Process for the preparation of dialkyl 2-vinylcyclopropane-1,1-dicarboxylates
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, (2008/06/13)
This invention relates to the preparation of dialkyl-2-vinylcyclopropane-1,1-dicarboxylates involving the addition of an alcoholic metallic alkoxide to an organic solution of a 1,4-dihalobutene-2 and a malonic ester.
PRODUCTION OF 1,1-DICHLORO-1-ALKENES BY THE ACTION OF ALKYLMAGNESIUM HALIDES ON 1,1,1-TRICHLORO-2-PROPENE
Zakharkin, L. I.,Zhigareva, G. G.
, p. 1831 - 1833 (2007/10/02)
The synthesis of 1,1-dichloro-1-alkenes was realized by the reaction of alkylmagnesium halides with 1,1,1-trichloro-2-propene. 2-Methyl-7-octadecyne, which is the main starting compound in the synthesis of Z-7,8-epoxy-2-methyloctadecane (Disparlure - the sex pheromone of Porthetria dispar), was obtained from 1,1-dichloro-1-dodecene.
Process for the preparation of halogen butenyl acrylates
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, (2008/06/13)
Halogenbutenylacrylates of formula STR1 in which R represents hydrogen or C1 -C4 alkyl and X represents halogen may be produced by reacting an acrylic acid salt of formula STR2 wherein M is ammonium, alkali metal or alkaline earth ion, with 1,4-di-halogen-butene-(2) in a diphasic system.