1733-52-4Relevant articles and documents
Reaction of 2H-azirine phosphine oxide and -phosphonates with nucleophiles. Stereoselective synthesis of functionalized aziridines and α- and β-aminophosphorus derivatives
Palacios, Francisco,Ochoa De Retana, Ana M.,Alonso, Jose M.
, p. 8895 - 8901 (2005)
A simple and efficient stereoselective synthesis of aziridine-2-phosphonate 3, and -phosphine oxide 5 by diastereoselective addition of Grignard reagents to 2H-azirine phosphonate 1 and -phosphine oxide 4 is reported. Similarly, the addition of heterocycl
Reaction of vinyl- and allenylphosphorylated compounds with cytisine in aqueous medium
Matveeva,Kovaleva, E. Yu.,Brel
, p. 2592 - 2595 (2015)
We have shown for the first time that the alkaloid cytisine can be easily involved in the reaction of nucleophilic addition with certain unsaturated phosphoryl compounds including vinylphosphonate, vinyl phosphine oxide, allenylphosphonates, and allenyl p
Copper-Catalyzed Decarboxylative Hydrophosphinylation of α-Acyl-α-Diazoacetates
Zhang, Can,Dong, Chao,Wang, Xin,Shen, Ruwei
supporting information, p. 7440 - 7444 (2020/12/01)
A simple copper-catalyzed decarboxylation–denitrogenation C–P coupling reaction of α-acyl-α-diazoacetates with hydrophosphoryl compounds is reported. The reaction may proceed via a process involving the generation of (diazomethyl)ketones after hydrolysis in the presence of water and the hydrophosphinylation of the copper carbene intermediates. This finding may suggest the potential use of the relatively more readily available α-acyl-α-diazoacetates as replacement of (diazomethyl)ketones in some cases.
Copper catalyzed one-pot synthesis of β-ketophosphine oxides from ketones and H-phosphine oxides
Zhang, Zhi-Jie,Yi, Dong,Fu, Qiang,Liang, Wu,Chen, Su-Yuan,Yang, Lu,Du, Feng-Tian,Ji, Jian-Xin,Wei, Wei
supporting information, p. 2417 - 2420 (2017/06/01)
A facile and efficient copper catalyzed one-pot method has been developed for the formation of β-ketophosphine oxides from ketones and H-phosphine oxides under air at room temperature, in which vinylhydrazinedicarboxylate was formed as the key intermediate. Preliminary mechanistic studies indicated that the reaction might involve a radical process and carbonyl oxygen atom of β-ketophosphine oxides came from molecular oxygen.
