17332-04-6

Basic information

• Product Name: 1H-Indene-2-carboxylic acid, methyl ester
• Synonyms: methoxycarbonyl-2 indene;methyl 2-indenecarboxylate;Methyl indene-2-carboxylate;2-Indencarbonsaeure-methylester;1H-Indene-2-carboxylic acid,methyl ester
• CAS NO: 17332-04-6
• Molecular Formula: C11H10O2
• Molecular Weight: 174.199
• Mol File: 17332-04-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1H-Indene-2-carboxylic acid, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indene-2-carboxylic acid, methyl ester(17332-04-6)
• EPA Substance Registry System: 1H-Indene-2-carboxylic acid, methyl ester(17332-04-6)

Safety Data

• Hazardous Substances Data: 17332-04-6(Hazardous Substances Data)

Upstream product

• 292638-85-8 acrylic acid methyl ester 
• 67-56-1 methanol 
• 70304-47-1 Naphtho<2,3-d><1,2,3>oxadiazol 
• 5464-07-3 3-acetoxy-2-naphthoic acid 

Downstream Products

• 90036-42-3 (3aR,8aS)-3-Benzyl-3a,8-dihydro-3H-indeno[1,2-d][1,2,3]triazole-8a-carboxylic acid methyl ester 
• 138250-43-8 3-hydroxy-1-(1-isoquinolinyl)-8a-methoxycarbonyl-3-phenyl-3,3a,8,8a-tetrahydroindenol<1,2-c>pyrrole 
• 18096-68-9 2-hydroxymethyl-1H-indene 
• 1356254-96-0 methyl (S)-3-[2-(methoxycarbonyl)-1-phenylallyl]-1H-indene-2-carboxylate 
• 138250-44-9 2,8-dihydro-1-(1-isoquinolinyl)-3-phenylindeno<1,2-c>pyrrole 
• 90036-54-7 3-Phenylamino-1H-indene-2-carboxylic acid methyl ester 
• 71168-07-5 (1aR,6aS)-1-Phenyl-1a,6-dihydro-1H-1-aza-cyclopropa[a]indene-6a-carboxylic acid methyl ester 
• 71168-04-2 (3aS,8aR)-3-Phenyl-3a,8-dihydro-3H-indeno[1,2-d][1,2,3]triazole-8a-carboxylic acid methyl ester 
• 70563-80-3 (1R,3aS,8aS)-2-Phenyl-1,2,3a,8-tetrahydro-indeno[1,2-c]pyrrole-1,3,3,8a-tetracarboxylic acid tetramethyl ester 
• 70563-77-8 (1S,3aS,8aS)-1,2-Diphenyl-1,2,3a,8-tetrahydro-indeno[1,2-c]pyrrole-3,3,8a-tricarboxylic acid trimethyl ester 

Relevant articles and documents

Synthesis and reactions of tetracarbonylmanganese complexes of benzoylsilanes

Reactions of benzoylsilane with benzylpentacarbonylmanganese (1) give ortho-η2-manganese complexes in high yield.The derived aldehyde complex can then be formed by fluoride-catalysed desilylation of the acylsilane complex.Coupling reactions of the acylsilane complexes with alkenes or alkynes are reported. Key words: Manganese; Carbonyl; Silane; Aldehyde; Alkene; Alkyne

Benzothiet-2-ones: Synthesis, Reactions, and Comparison with Benzoxet-2-ones and Benzazetin-2-ones

Benzothiet-2-one (5) is obtained as a neat solid, stable below -20 deg C(-45 deg C in solution), by flash vacuum pyrolysis of benzothiophene-2,3-dione (9).Naphthothiet-2-one (21) and naphthothiet-1-one (42) are obtained as stable crystalline solids in near-quantitative yields from the corresponding naphthothiophenediones 20 and 41.Naphthooxet-2-one (31) and naphthoazetin-2-one (36) were generated and observed by IR spectroscopy to be stable below -40 deg C and 0 deg C, respectively.The thietones, oxetones, and azetinones undergo rapid ring-opening reactions with methanol to give the corresponding carboxylic acid esters.They undergo thermal CO elimination with concomitant Wolff-type ring contraction to thioketenes (17, 25, 45), ketenes (30), and nitriles (37), respectively.The di-, oligo-, and polymerization of the thietones has been elucidated.Naphthothiet-1-one (42) reacts with 1-thiocarbonyl-1H-indene (45) to give cycloaddition product 46.Naphthothietones 21 and 42 react with dicyclohexylcarbodiimide to furnish 2-imino-1,3-thiazin-4-one derivatives 47 and 49.