173593-27-6

Basic information

• Product Name: 2-Propenoic acid, 3-(3-methylphenyl)-, butyl ester, (2E)-
• CAS NO: 173593-27-6
• Molecular Formula: C14H18O2
• Molecular Weight: 218.296
• Mol File: 173593-27-6.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(3-methylphenyl)-, butyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(3-methylphenyl)-, butyl ester, (2E)-(173593-27-6)
• EPA Substance Registry System: 2-Propenoic acid, 3-(3-methylphenyl)-, butyl ester, (2E)-(173593-27-6)

Safety Data

• Hazardous Substances Data: 173593-27-6(Hazardous Substances Data)

Upstream product

• 3029-79-6 (E)-3-methylcinnamic acid 
• 71-36-3 butan-1-ol 
• 28987-79-3 m-tolylmagnesium bromide 
• 591-17-3 meta-bromotoluene 
• 3333-20-8 1-allyl-3-methylbenzene 
• 141-32-2 acrylic acid n-butyl ester 
• 17933-03-8 m-tolylboronic acid 
• 15898-38-1 sodium 3-methylbenzenesulfinate 
• 108-88-3 toluene 
• 625-95-6 3-Iodotoluene 

Relevant articles and documents

Palladium nanoparticles encapsulated in polyimide nanofibers: An efficient and recyclable catalyst for coupling reaction

In this study, palladium-encapsulated poly(amic acid) (Pd@PAA) nanofibers were prepared by electrospinning, followed by thermal imidization to synthesize palladium-encapsulated polyimide (Pd@PI) nanofibers. Scanning electron microscopy (SEM) images confirmed the preparation of uniform and smooth Pd@PAA and Pd@PI nanofibers. Thermogravimetric analysis (TGA) results reveal that the Pd@PI nanofibers possessed excellent thermal stability. The dispersion of palladium nanoparticles in the polyimide nanofibers was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The catalysis results show that this Pd@PI fibrous catalyst was very efficient to catalyze the cross-coupling reactions of aromatic iodides with n-butyl acrylate (Heck reaction) or phenylboronic acid derivatives (Suzuki reaction) to afford the desired products in good to excellent yields. Moreover, the Pd@PI catalyst could be easily separated and recovered from the reaction mixture by simple filtration due to the regular fibrous structure and reused for 10 times for both Heck and Suzuki reactions without obvious loss of its initial catalytic activity. Thus, the Pd@PI nanofiber catalyst holds great potential in chemical industry in terms of its excellent catalytic activity and stability.

Encapsulating palladium nanoparticles inside ethylenediamine functionalized and crosslinked chlorinated poly(vinyl chloride) nanofibers as an efficient and stable heterogeneous catalyst for coupling reactions

Palladium chloride and chlorinated poly (vinyl chloride) (CPVC) mixture were prepared into homogeneous solution, followed by electrospinning to make uniform nanofibers with average diameter of ~460 nm. Then, these composite nanofibers were treated in ethy

NHC stabilized Pd nanoclusters in the Mizoroki-Heck reaction within microemulsion: exploring the role of imidazolium salt in rate enhancement

We report the significant rate enhancement of the Mizoroki-Heck reaction by in situ generated palladium nanoclusters within the confined space of water-in-oil (w/o) mixed microemulsion (μE) formulated by sodium dodecylsulfate (SDS), polyoxyethylene (23) l