173597-19-8

Upstream product

• 28541-75-5 p-methoxyphenyl α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 17042-40-9 4-methoxyphenyl 2,3,4,6-tetra-O-acetyl-1-α-D-mannopyranoside 
• 4132-28-9 2,3,4,6-tetra-O-benzyl-D-mannopyranose 
• 5720-07-0 4-methoxyphenylboronic acid 
• 7294-51-1 2,4,6-tris(4-methoxyphenyl)boroxine 

Downstream Products

• 4132-28-9 2,3,4,6-tetra-O-benzyl-D-mannopyranose 
• 1339956-59-0 p-methoxyphenyl 2,3,4-tri-O-benzyl-6-O-dimethylphenylsilyl-α-D-mannopyranoside 
• 1206803-29-3 p-methoxyphenyl 2,3,4-tri-O-benzyl-6-O-triethyl-silyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

Copper-mediated anomeric: O -arylation with organoboron reagents

Copper-mediated couplings of arylboroxines with glycosyl hemiacetals furnish O-aryl glycosides via Csp2-O bond formation. The method enables the anomeric O-arylation of protected pyranose and furanose derivatives, and is tolerant of functionalized arylboroxine partners. Whereas mixtures of anomers are formed from glucopyranose, galactopyranose and arabinofuranose hemiacetals, the α-anomer is generated selectively from mannopyranose and mannofuranose-derived substrates.