17378-82-4

Basic information

• Product Name: bis(1,10-phenanthroline)copper(1+) ion
• Synonyms: bis(1,10-phenanthroline)copper(1+) ion
• CAS NO: 17378-82-4
• Molecular Formula: C₂₄H₁₆CuN₄
• Molecular Weight: 0
• Mol File: 17378-82-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 164.8°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 3.38E-05mmHg at 25°C
• CAS DataBase Reference: bis(1,10-phenanthroline)copper(1+) ion(CAS DataBase Reference)
• NIST Chemistry Reference: bis(1,10-phenanthroline)copper(1+) ion(17378-82-4)
• EPA Substance Registry System: bis(1,10-phenanthroline)copper(1+) ion(17378-82-4)

Safety Data

• Hazardous Substances Data: 17378-82-4(Hazardous Substances Data)

Usage

InChI:InChI=1/2C12H8N2.Cu/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h2*1-8H;/q;;+1

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 938512-00-6 ortho-iodobenzoylglycilglycine 
• 7732-18-5 water 
• 1145-32-0 N-(N'-benzoyl-2-aminoethanoyl)-2-aminoethanoic acid 
• 495-69-2 Hippuric Acid 
• 7681-65-4 copper(l) iodide 
• 106-38-7 para-bromotoluene 
• 105-67-9 2,4-Xylenol 
• 64443-05-6 tetrakis(actonitrile)copper(I) hexafluorophosphate 
• 1613741-33-5 2-(6-(2,4,6-trimethylphenyl)pyridin-2-yl)-9-(2,4,6-trimethylphenyl)[1,10]phenanthroline 
• 7789-45-9 copper(ll) bromide 

Downstream Products

• 15823-71-9 bis(1,10-phenanthroline)copper⁽²⁺⁾ 

Relevant articles and documents

On the origin of copper(i) catalysts from copper(ii) precursors in C-N and C-O cross-couplings

CuII precursors ligated to phenanthrolines are reduced in situ by alcohols or amines in the presence of a base (Cs2CO3) to generate CuI species which are active catalysts in C-N and C-O cross-coupling reactions. The conversion CuII → CuI has been evidenced and monitored by UV-vis and NMR spectroscopy.

Reversible cargo shipping between orthogonal stations of a nanoscaffold upon redox input

The sterically shielded terpyridine 5 was prepared, both as a new ligand and as part of the four-station nanoscaffold 2. Mixing of terpyridine 5, the parent phenanthroline 4 and the shielded phenanthroline 3 in the presence of Zn2+ (1:1:1:1) fu