17428-98-7Relevant articles and documents
Vicinal Diboration of Alkyl Bromides via Tandem Catalysis
Wang, Xiao-Xu,Li, Lei,Gong, Tian-Jun,Xiao, Bin,Lu, Xi,Fu, Yao
, p. 4298 - 4302 (2019/06/14)
Vicinal diboration of alkyl bromides via tandem catalysis is reported. The reported reaction exhibits a broad substrate scope, good functional group compatibility, and regioselectivity. Moreover, it shows good practicality due to the easy accessibility of alkyl bromides in combination with diverse transformations of diboronates. Mechanism study indicates that terminal alkenes are generated selectively through nickel-catalyzed dehydrohalogenation of alkyl bromides followed by base/MeOH promoted diboration process to provide 1,2-diboration products.
Isomerisation reaction of a gem-bis-trifluoromethyl olefin in a basic medium: A kinetic study
Tordeux, Marc,Marival-Hodebar, Laurence,Pouet, Marie-Josée,Halle, Jean-Claude,Wakselman, Claude
, p. 147 - 152 (2007/10/03)
The rearrangement of 5-phenyl-1,1,1-trifluoro-2-(trifluoromethyl)pent-2-ene to 5-phenyl-1,1,1-trifluoro-2-(trifluoromethyl)pent-3-ene has been studied by 19F NMR in dimethylsulphoxide (DMSO). This isomerisation is catalysed by a base such as tr
