19136-97-1

Basic information

• Product Name: HYDROCINNAMIC-2,2-D2 ACID
• Synonyms: HYDROCINNAMIC-2,2-D2 ACID;HydrocinnaMic--d2 Acid
• CAS NO: 19136-97-1
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 152.19
• Mol File: 19136-97-1.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: HYDROCINNAMIC-2,2-D2 ACID(CAS DataBase Reference)
• NIST Chemistry Reference: HYDROCINNAMIC-2,2-D2 ACID(19136-97-1)
• EPA Substance Registry System: HYDROCINNAMIC-2,2-D2 ACID(19136-97-1)

Safety Data

• Hazardous Substances Data: 19136-97-1(Hazardous Substances Data)

Usage

Uses

Hydrocinnamic-alpha,alpha-d2 Acid (CAS# 19136-97-1) is a useful isotopically labeled research compound.

Upstream product

• 103-25-3 3-phenylpropanoic acid methyl ester 
• 3709-27-1 5-benzyl-2,2-dimethyl-1,3-dioxane-4,6-dione 
• 114-84-1 phenylpropionic acid sodium salt 
• 103-82-2 phenylacetic acid 
• 29372-33-6 α,α-dideuterated hydrocinnamaldehyde 
• 1186-52-3 tetradeuterioacetic acid 
• 100-39-0 benzyl bromide 
• 104-53-0 3-phenyl-propionaldehyde 
• 124-38-9 carbon dioxide 
• 15785-29-2 1,1,-d²-2-phenylethyl bromide 
• 40638-92-4 1,1-dideuterio-2-phenylethanol 

Downstream Products

• 51086-43-2 2-[D₂]-4-phenylbutanoic acid 
• 83025-97-2 C₁₆H₁₆⁽²⁾H₂O₃S 
• 83025-98-3 C₁₅H₁₄⁽²⁾H₂OSe 
• 83026-03-3 C₁₅H₁₄⁽²⁾H₂Se 
• 60468-24-8 (2-deuterio-2-propenyl)benzene 
• 61233-28-1 α,α-Dideutero-3-phenylpropionylchlorid 
• 17428-98-7 2-[D₂]-3-phenylpropan-1-ol 

Relevant articles and documents

Controllable Intramolecular Unactivated C(sp3)-H Amination and Oxygenation of Carbamates

Dual catalyst-controlled intramolecular unactivated C(sp3)-H amination and oxygenation of carbamates merging visible-light photocatalysis and earth-abundant transition metal catalysis have been reported. Useful amino alcohol and diol derivatives could be selectively obtained from readily available tertiary alcohol derivatives. The possible mechanisms have been proposed via a 1,5-HAT process followed by Lewis acid-controlled cyclization. The nickel and zinc catalysts inhibit the formation of oxygenation and amination products, respectively. An interesting phenomenon of chirality transfer is also observed.

Triazolium Carbene Catalysts and Stereoselective Bond Forming Reactions Thereof

Provided herein are triazolium carbine catalysts useful for asymmetric hydration, fluorination, and deuteration, and processes for their preparation. Also provided are synthetic reactions in which these catalysts are used, in particular, in stereoselective formation of carbon-chlorine, carbon-hydrogen, carbon-fluorine, and carbon-deuterium bonds.

Isomerisation reaction of a gem-bis-trifluoromethyl olefin in a basic medium: A kinetic study

The rearrangement of 5-phenyl-1,1,1-trifluoro-2-(trifluoromethyl)pent-2-ene to 5-phenyl-1,1,1-trifluoro-2-(trifluoromethyl)pent-3-ene has been studied by 19F NMR in dimethylsulphoxide (DMSO). This isomerisation is catalysed by a base such as tr