17429-00-4

Basic information

• Product Name: 3-Methoxycyclohexanone
• Synonyms: 3-Methoxycyclohexanone;Cyclohexanone, 3-methoxy-
• CAS NO: 17429-00-4
• Molecular Formula: C₇H₁₂O₂
• Molecular Weight: 128.17
• Mol File: 17429-00-4.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 189.3°C at 760 mmHg
• Flash Point: 68.8°C
• Appearance: /
• Density: 0.98g/cm³
• Vapor Pressure: 0.574mmHg at 25°C
• Refractive Index: 1.44
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 3-Methoxycyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methoxycyclohexanone(17429-00-4)
• EPA Substance Registry System: 3-Methoxycyclohexanone(17429-00-4)

Safety Data

• Hazardous Substances Data: 17429-00-4(Hazardous Substances Data)

Usage

General Description

3-Methoxycyclohexanone, also known as MCH, is a chemical compound with the molecular formula C8H14O2. It is a colorless liquid with a strong, sweet odor. It is commonly used as a flavoring agent in the food industry and as a fragrance in the cosmetic and personal care products. MCH is also used as an intermediate in the synthesis of pharmaceuticals and agrochemicals. It is a highly versatile compound, with its applications extending to the production of resins, polymers, and other industrial chemicals. In addition, MCH is known for its low toxicity and environmentally friendly properties, making it a popular choice in various industrial and commercial applications.

InChI:InChI=1/C7H12O2/c1-9-7-4-2-3-6(8)5-7/h7H,2-5H2,1H3

Upstream product

• 504-01-8 cyclohexane-1,3-diol 
• 74-88-4 methyl iodide 
• 150-19-6 O-methylresorcine 
• 67-56-1 methanol 
• 110-83-8 cyclohexene 
• 930-68-7 cyclohexenone 
• 765-87-7 cyclohexane-1,2-dione 
• 114377-54-7 1,1,3-trimethoxycyclohexane 

Downstream Products

• 1459-31-0 2-cyclohexenone 2,4-dinitrophenylhydrazone 
• 531-59-9 7-methoxycoumarin 
• 150-19-6 O-methylresorcine 

Relevant articles and documents

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Ductile Pd-Catalysed Hydrodearomatization of Phenol-Containing Bio-Oils Into Either Ketones or Alcohols using PMHS and H2O as Hydrogen Source

A series of phenolic bio-oil components were selectively hydrodearomatized by palladium on carbon into the corresponding ketones or alcohols in excellent yields using polymethylhydrosiloxane and water as reducing agent. The selectivity of the reaction was governed by the water concentration where selectivity to alcohol was favoured at higher water concentrations. As phenolic bio-oil examples cardanol and beech wood tar creosote were studied as substrate to the developed reaction conditions. Cardanol was hydrodearomatized into 3-pentadecylcyclohexanone in excellent yield. From beech wood tar creosote, a mixture of cyclohexanols was produced. No hydrodeoxygenation occurred, suggesting the applicability of the reported method for the production of ketone-alcohol oil from biomass. (Figure presented.).

Triazolium salts as appropriate catalytic scaffolds for 1,4-additions to α,β-unsaturated carbonyls

1,2,3-Triazole derivatives containing a rigid dihydroanthracenyl skeleton are suitable precursors for both organometallic and organo-based catalysts. A Rh-carbene complex and the triazolium salt efficiently catalyzed the 1,4-additions of C- and heterodonor reagents to α,β-unsaturated carbonyl substrates, respectively. Copyright

Catalytic behavior of melamine glyoxal resin towards consecutive oxidation and oxy-Michael addition

Synthesis of melamine glyoxal resin involves a catalyst-free, one pot reaction between melamine and glyoxal in DMF. The synthesized resins have a similar morphological arrangement to that of layered materials as depicted by their XRD pattern and Raman spectra. The catalytic behavior of melamine glyoxal resin (MGR) have been studied in allylic oxidation of cyclohexene and simultaneous Michael addition. The MGR/solvent/O2 oxidant system can be regarded as a metalfree, additive-free, cost-effective and environmentally benign catalytic system. The oxidative behavior of MGR is attributed to its ability to generate in situ organic peroxide species during the course of reaction. Generation of peroxide species is confirmed by the KI/starch test and further confirmed by the complete suppression effect of TEMPO (2,2,6,6- tetramethylpiperidine-1-oxyl) over oxidation. The activity for Michael addition can be attributed to the presence of a higher content of nitrogen atoms, which serves as the active site. In oxidation, 28.1% conversion of cyclohexene with 37.19 and 62.81% selectivities for cyclohexenol and cyclohexenone were observed, respectively. In consecutive oxidation and oxy-Michael addition, 31.5% conversion of cyclohexene was observed with selectivities of 61.6% for cyclohexenone and 38.4% for alkoxy product. Springer Science+Business Media B.V. 2010.