1745-17-1

Basic information

• Product Name: 6-Heptenoic acid methyl ester
• Synonyms: 6-Heptenoic acid methyl ester;Methyl 6-heptenoate;Methyl 6-heptenoate >=95% (GC)
• CAS NO: 1745-17-1
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 142.2
• Mol File: 1745-17-1.mol
• Article Data: 22

Chemical Properties

• Flash Point: 61℃
• Appearance: /
• Density: 0.909 g/mL at 25 °C
• Refractive Index: n20/D1.426
• BRN: 1750178
• CAS DataBase Reference: 6-Heptenoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Heptenoic acid methyl ester(1745-17-1)
• EPA Substance Registry System: 6-Heptenoic acid methyl ester(1745-17-1)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-50
• Safety Statements: 61
• RIDADR: UN 3082 9/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 1745-17-1(Hazardous Substances Data)

Usage

General Description

6-Heptenoic acid methyl ester is a chemical compound with the molecular formula C8H14O2. It is a colorless liquid with a fruity odor, and it is used as a flavoring agent in the food and beverage industry. It is also utilized in the production of perfumes and as a fragrance ingredient in personal care products. Additionally, 6-Heptenoic acid methyl ester has potential applications in the pharmaceutical industry for drug synthesis. Its appealing fruity aroma makes it a popular choice for enhancing the sensory qualities of various consumer goods.

Upstream product

• 56909-02-5 methyl hept-6-ynoate 
• 67-56-1 methanol 
• 1119-60-4 hept-6-enoic acid 
• 75613-59-1 6-Hydroxy-7-trimethylsilanyl-heptanoic acid methyl ester 
• 2777-58-4 methyl petroselinate 
• 74-85-1 ethene 
• 52239-62-0 methyl 2-methoxy-3-methylbenzoate 
• 6654-36-0 methyl 6-oxohexanoate 
• 19493-09-5 Methylenetriphenylphosphorane 
• 196494-62-9 2-Phenylsulfanyl-hept-6-enoic acid methyl ester 
• 74785-92-5 methyl 7-phenylselenylheptanoate 
• 82302-70-3 8-oxo-4Z-octenoic acid methyl ester 
• 23895-60-5 tri-n-butylstannyldibromomethane 
• 186581-53-3 diazomethane 

Downstream Products

• 101254-69-7 8-benzylsulfanyl-6-chloro-octanoic acid methyl ester 
• 41138-69-6 7-{3-[(tert-butyldimethylsilanyl)oxy]-5-oxocyclopent-1-en-1-yl}heptanoic acid methyl ester 
• 144190-30-7 2,3-Di-pent-4-enyl-succinic acid dimethyl ester 
• 1119-60-4 hept-6-enoic acid 
• 176101-43-2 2-Benzyl-hept-6-enoic acid methyl ester 
• 342418-76-2 [2-(1-allyloxy-1-vinyl-allyl)-hept-6-enyl]-benzene 
• 1026647-45-9 7-[(1R,2R,3R,5S)-5-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-2-((E)-(S)-3-hydroxy-oct-1-enyl)-cyclopentyl]-heptanoic acid methyl ester 
• 251292-82-7 7-{(1R,2R,5S)-5-Acetoxy-2-[(E)-(S)-3-(tert-butyl-diphenyl-silanyloxy)-oct-1-enyl]-3-oxo-cyclopentyl}-heptanoic acid methyl ester 
• 251292-81-6 7-{(1R,2R,3R,5S)-5-Acetoxy-2-[(E)-(S)-3-(tert-butyl-diphenyl-silanyloxy)-oct-1-enyl]-3-hydroxy-cyclopentyl}-heptanoic acid methyl ester 
• 251292-77-0 7-{(1R,2R,3R,5S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-(S)-3-(tert-butyl-diphenyl-silanyloxy)-oct-1-enyl]-5-hydroxy-cyclopentyl}-heptanoic acid methyl ester 
• 251292-80-5 7-{(1R,2R,3R,5S)-5-Acetoxy-3-(tert-butyl-dimethyl-silanyloxy)-2-[(E)-(S)-3-(tert-butyl-diphenyl-silanyloxy)-oct-1-enyl]-cyclopentyl}-heptanoic acid methyl ester 
• 251292-78-1 7-{(1R,2R,3R,5S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-2-[(E)-(S)-3-(tert-butyl-diphenyl-silanyloxy)-oct-1-enyl]-cyclopentyl}-heptanoic acid methyl ester 
• 1121-66-0 2-Cyclohepten-1-one 
• 116349-04-3 (6S)-(-)-methyl 6,8-dihydroxyoctanoate 

Relevant articles and documents

Tandem RCM-Pauson-Khand reaction for access to tricycles in one step

Starting from conveniently designed dienynes complexed to cobalt, a tandem RCM-intramolecular Pauson-Khand reaction yields tricyclic compounds. The methodology allows the synthesis of 6,5,5 and 7,5,5 systems.

Chemoselectivity in the Chromium(II)-Mediated Synthesis of E-Alkenylstannanes from Aldehydes and Bu3SnCHBr2

The synthesis of functionalised E-alkenylstannanes from aldehydes and a mixture of Bu3SnCHBr2, LiI and CrCl2 is described.

Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope

A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.

Enantioselective allylic hydroxylation of w-alkenoic acids and esters by P450 BM3 monooxygenase

Chiral allylic alcohols of w-alkenoic acids and derivatives thereof are highly important building blocks for the synthesis of biologically active compounds. The direct enantioselective C-H oxidation of linear terminal olefins offers the shortest route toward these compounds, but known synthetic methods are limited and suffer from low selectivities. Described herein is an enzymatic approach using the P450 BM3 monooxygenase mutant A74G/L188Q, which catalyzes allylic hydroxylation with high to excellent chemo- and enantioselectivities providing the desirable secondary alcohols.