1747-92-8

Usage

Uses

Used in Organic Chemistry:
TRIBENZYLSILANE is used as a reducing agent for the reduction of functional groups such as ketones, aldehydes, and olefins. It facilitates the conversion of these groups into their corresponding alcohols, which is crucial for the synthesis of various organic compounds.
Used in Pharmaceutical Synthesis:
TRIBENZYLSILANE is used as a reagent in the synthesis of pharmaceuticals. Its reducing capabilities and protective properties for functional groups are essential in the production of complex organic molecules that are used as active pharmaceutical ingredients.
Used in Agrochemical Production:
TRIBENZYLSILANE is used in the synthesis of agrochemicals, where its role as a reducing agent and protective agent for functional groups is vital for creating effective compounds used in agriculture to protect crops and enhance yields.
Used as a Protective Agent:
TRIBENZYLSILANE is used as a protective agent for functional groups during chemical reactions. This helps to prevent unwanted side reactions and ensures the desired product is formed, which is particularly important in the synthesis of complex organic molecules.
Used as a Stabilizer for Reactive Intermediates:
TRIBENZYLSILANE is used as a stabilizer for certain reactive intermediates in organic synthesis. Its ability to stabilize these intermediates allows for the successful completion of multi-step reactions, contributing to the overall efficiency and yield of the synthesis process.

InChI:InChI=1/C21H21Si/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2

Upstream product

• 1589-82-8 phenylmagnesium bromide 
• 60-29-7 diethyl ether 
• 998-30-1 Triethoxysilane 
• 6921-34-2 benzylmagnesium chloride 
• 15458-91-0 dibenzyl-silane 
• 766-06-3 benzylsilane 
• 10025-78-2 trichlorosilane 
• 18414-36-3 dibenzyldichlorosilane 

Downstream Products

• 18848-73-2 tribenzyl-hexyl-silane 
• 18758-62-8 tribenzyl-nonyl-silane 
• 18866-37-0 tribenzyl-octyl-silane 
• 18885-14-8 oxo-bis 
• 18740-59-5 tribenzylchlorosilane 
• 18790-70-0 (3-Phenoxy-phenyl)-tribenzyl-silan 
• 18870-52-5 <4-Brom-phenyl>-tribenzyl-silan 
• 18840-85-2 p-Phenylen-bis- 
• 18762-96-4 o-Tolyl-tribenzyl-silan 
• 18842-18-7 Tribenzyl-p-biphenylyl-silan 
• 18763-05-8 m-Tolyl-tribenzyl-silan 
• 18790-71-1 (2-Phenoxy-phenyl)-tribenzyl-silan 
• 18790-72-2 <4-Phenoxy-phenyl>-tribenzyl-silan 
• 18842-53-0 <4-Trimethylsilyl-phenyl>-tribenzyl-silan 

Relevant academic research and scientific papers

A general route to five-coordinate hydridosilicates

Five-coordinate potassium hydridosilicates, - K+ (R=Et, i-Pr, Ph), have been obtained in good yield from the reaction of a trialkoxy- or triaryloxy-silane with the corresponding potassium alkoxide or aryloxide, and characterized spectroscopically.Reaction of the hydrosilicates with an excess of Grignard reagent gives the corresponding triorganosilanes.

New hexacoordinate silicon complexes, the process for their preparation and their application

The present invention relates to new hexacoordinate silicon complexes, the process for their preparation and their application. These new complexes correspond to the general formula I: STR1 in which: A represents an alkali metal or alkaline earth metal except for magnesium, and n=0 or 1.

Five-coordinate potassium dihydridosilicates: synthesis and some aspects of their reactivity

Five-coordinate potassium dihydridosilicates, K+- (R = Et, i-Pr) have been obtained by reaction of a trialkoxysilane with potassium hydride.Reaction of the dihydridosilicate with an excess of a Grignard reagent gives the corresponding diorganosilane.The ease of reduction of carbonyl compounds by the dihydridosilicate in the absence of a catalyst is indicative of the high reactivity of the Si-H bond in such species.

Hypervalent silicon hydrides: evidence for their intermediacy in the exchange reactions of di- and tri-hydrogenosilanes catalysed by hydrides (NaH, KH and LiAlH4)

Di and tri-hydrogenosilanes, RR'SiH2 and RSiH3 (R=aryl, allyl or benzyl; R'=aryl or alkyl), readily undergo exchange reactions, involving silicon-carbon bonds and silicon-hydrogen bonds, in the presence of hydrides (LiAlH4, KH and NaH) as catalysts.These results are discussed in terms of five-coordinate silicon hydrides as intermediates in the reaction.