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TRIBENZYLSILANE, with the molecular formula C21H22Si, is a colorless to yellow clear liquid that is insoluble in water. It is a chemical compound that serves as a versatile reagent in organic chemistry, known for its reducing properties and its ability to protect functional groups during chemical reactions.

1747-92-8

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1747-92-8 Usage

Uses

Used in Organic Chemistry:
TRIBENZYLSILANE is used as a reducing agent for the reduction of functional groups such as ketones, aldehydes, and olefins. It facilitates the conversion of these groups into their corresponding alcohols, which is crucial for the synthesis of various organic compounds.
Used in Pharmaceutical Synthesis:
TRIBENZYLSILANE is used as a reagent in the synthesis of pharmaceuticals. Its reducing capabilities and protective properties for functional groups are essential in the production of complex organic molecules that are used as active pharmaceutical ingredients.
Used in Agrochemical Production:
TRIBENZYLSILANE is used in the synthesis of agrochemicals, where its role as a reducing agent and protective agent for functional groups is vital for creating effective compounds used in agriculture to protect crops and enhance yields.
Used as a Protective Agent:
TRIBENZYLSILANE is used as a protective agent for functional groups during chemical reactions. This helps to prevent unwanted side reactions and ensures the desired product is formed, which is particularly important in the synthesis of complex organic molecules.
Used as a Stabilizer for Reactive Intermediates:
TRIBENZYLSILANE is used as a stabilizer for certain reactive intermediates in organic synthesis. Its ability to stabilize these intermediates allows for the successful completion of multi-step reactions, contributing to the overall efficiency and yield of the synthesis process.

Check Digit Verification of cas no

The CAS Registry Mumber 1747-92-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,4 and 7 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1747-92:
(6*1)+(5*7)+(4*4)+(3*7)+(2*9)+(1*2)=98
98 % 10 = 8
So 1747-92-8 is a valid CAS Registry Number.
InChI:InChI=1/C21H21Si/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2

1747-92-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Tribenzylsilane

1.2 Other means of identification

Product number -
Other names Tribenzyl-silan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1747-92-8 SDS

1747-92-8Relevant academic research and scientific papers

A general route to five-coordinate hydridosilicates

Becker, B.,Corriu, R.,Guerin, C.,Henner, B.,Wang, Q.

, p. C33 - C35 (1989)

Five-coordinate potassium hydridosilicates, - K+ (R=Et, i-Pr, Ph), have been obtained in good yield from the reaction of a trialkoxy- or triaryloxy-silane with the corresponding potassium alkoxide or aryloxide, and characterized spectroscopically.Reaction of the hydrosilicates with an excess of Grignard reagent gives the corresponding triorganosilanes.

Five-coordinate potassium dihydridosilicates: synthesis and some aspects of their reactivity

Becker, B.,Corriu, R. J. P.,Guerin, C.,Henner, B.,Wang, Q.

, p. C25 - C28 (2007/10/02)

Five-coordinate potassium dihydridosilicates, K+- (R = Et, i-Pr) have been obtained by reaction of a trialkoxysilane with potassium hydride.Reaction of the dihydridosilicate with an excess of a Grignard reagent gives the corresponding diorganosilane.The ease of reduction of carbonyl compounds by the dihydridosilicate in the absence of a catalyst is indicative of the high reactivity of the Si-H bond in such species.

Hypervalent silicon hydrides: evidence for their intermediacy in the exchange reactions of di- and tri-hydrogenosilanes catalysed by hydrides (NaH, KH and LiAlH4)

Becker, B.,Corriu, R. J. P.,Guerin, C.,Henner, B. J. L.

, p. 147 - 154 (2007/10/02)

Di and tri-hydrogenosilanes, RR'SiH2 and RSiH3 (R=aryl, allyl or benzyl; R'=aryl or alkyl), readily undergo exchange reactions, involving silicon-carbon bonds and silicon-hydrogen bonds, in the presence of hydrides (LiAlH4, KH and NaH) as catalysts.These results are discussed in terms of five-coordinate silicon hydrides as intermediates in the reaction.

New hexacoordinate silicon complexes, the process for their preparation and their application

-

, (2008/06/13)

The present invention relates to new hexacoordinate silicon complexes, the process for their preparation and their application. These new complexes correspond to the general formula I: STR1 in which: A represents an alkali metal or alkaline earth metal except for magnesium, and n=0 or 1.

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