175136-27-3 Usage
Explanation
The molecular formula represents the number of atoms of each element present in a molecule. In this case, the compound has 17 carbon (C) atoms, 27 hydrogen (H) atoms, 1 nitrogen (N) atom, and 1 oxygen (O) atom.
Explanation
The structure describes the arrangement of atoms and groups within the molecule. It consists of a tert-butyl group, a 1,1-dimethyl-2,3-dihydro-1H-inden-4-yl group, and an ethan-1-one oxime moiety.
Explanation
These groups are responsible for the compound's chemical properties and reactivity. The tert-butyl group is a bulky, non-reactive group, while the 1,1-dimethyl-2,3-dihydro-1H-inden-4-yl group and ethan-1-one oxime moiety contribute to the compound's reactivity and potential applications.
Explanation
The compound's unique structure and functional groups make it suitable for use as a ligand, which can help stabilize and control the reactivity of metal complexes in organic chemistry.
Explanation
Due to its versatile structure and reactivity, the compound can be used in the synthesis of a wide range of chemicals, including those used in the pharmaceutical and agrochemical industries.
Explanation
The compound's unique structure and functional groups may also make it useful as a catalyst or reagent in various organic synthesis reactions, further expanding its potential applications.
Structure
1-[6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]ethan-1-one oxime
Functional Groups
Tert-butyl group, 1,1-dimethyl-2,3-dihydro-1H-inden-4-yl group, and ethan-1-one oxime moiety
Application
Used as a ligand in organic chemistry and in the synthesis of various organic compounds
Industrial Applications
Production of pharmaceuticals, agrochemicals, and other specialty chemicals
Additional Uses
Catalyst or reagent in organic synthesis
Check Digit Verification of cas no
The CAS Registry Mumber 175136-27-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,5,1,3 and 6 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 175136-27:
(8*1)+(7*7)+(6*5)+(5*1)+(4*3)+(3*6)+(2*2)+(1*7)=133
133 % 10 = 3
So 175136-27-3 is a valid CAS Registry Number.
InChI:InChI=1/C17H25NO/c1-11(18-19)14-9-12(16(2,3)4)10-15-13(14)7-8-17(15,5)6/h9-10,19H,7-8H2,1-6H3/b18-11+
175136-27-3Relevant academic research and scientific papers
Mizoroki-Heck Reaction of Unstrained Aryl Ketones via Ligand-Promoted C-C Bond Olefination
Wang, Mei-Ling,Xu, Hui,Li, Han-Yuan,Ma, Biao,Wang, Zhen-Yu,Wang, Xing,Dai, Hui-Xiong
supporting information, p. 2147 - 2152 (2021/04/05)
Mizoroki-Heck reaction of unstrained aryl ketone with acrylate/styrene is accomplished via palladium-catalyzed ligand-promoted C-C bond cleavage. Various (hetero)aryl ketones are compatible in the reaction, affording the alkene product in good to excellent yields. Further applications in the late-stage olefination of some drugs, natural products, and fragrance-derived aryl ketones demonstrate the synthetic utility of this protocol. By employing ketone as both the directing group and the leaving group, 1,2-bifunctionalization is achieved via sequential ortho-C-H alkylation/ipso-Heck olefination.
Arylketones as Aryl Donors in Palladium-Catalyzed Suzuki-Miyaura Couplings
Wang, Zhen-Yu,Ma, Biao,Xu, Hui,Wang, Xing,Zhang, Xu,Dai, Hui-Xiong
supporting information, p. 8291 - 8295 (2021/11/13)
Herein, we report the arylation, alkylation, and alkenylation of aryl ketones via a palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. The use of the pyridine-oxazoline ligand is the key to the cleavage of the unstrained C-C bond. The late-stage arylation of aryl ketones derived from drugs and natural products demonstrated the synthetic utility of this protocol.
Aza-retinoids as novel retinoid X receptor-specific agonists
Farmer, Luc J.,Marron, Kristen S.,Canan Koch, Stacie S.,Hwang,Kallel, E. Adam,Zhi, Lin,Nadzan, Alex M.,Robertson, Dave W.,Bennani, Youssef L.
, p. 2352 - 2356 (2007/10/03)
A new structurally simple series of potent lipophilic aza-retinoids RXR agonists has been developed. SAR studies for the N-alkyl-azadienoic acids described here demonstrate that the RXR activity profile is sensitive to the N-alkyl chain length. Further, we have expanded the work to include azadienoic acids, which exhibited many accessible conformations leading to a better understanding of the SAR around the series.
