175656-41-4Relevant academic research and scientific papers
Stereocontrolled synthesis of E-homoallylic sulfides with 1,4,5 related chiral centres using the [2,3] sigmatropic rearrangement of sulfonium ylides
Hartley, Richard C.,Richards, Ian C.,Warren, Stuart
, p. 359 - 376 (1996)
E-Homoallylic sulfides with 1,4,5 related chiral centres have been synthesised in a stereocontrolled way. An aldol condensation sets up the stereochemistry. Lactonisation with 1,2 arylsulfanyl migration followed by reduction and sulfur-assisted dehydratio
