Stereocontrolled synthesis of E-homoallylic sulfides with 1,4,5 related chiral centres using the [2,3] sigmatropic rearrangement of sulfonium ylides

DOI: 10.1039/p19960000359

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Journal of the Chemical Society. Perkin transactions I p. 359 - 376 (1996)

Update date:2022-08-02

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Authors:

Hartley, Richard C.

Richards, Ian C.

Warren, Stuart

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Article abstract of DOI:10.1039/p19960000359

E-Homoallylic sulfides with 1,4,5 related chiral centres have been synthesised in a stereocontrolled way. An aldol condensation sets up the stereochemistry. Lactonisation with 1,2 arylsulfanyl migration followed by reduction and sulfur-assisted dehydratio

Full text of DOI:10.1039/p19960000359

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