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175883-63-3

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175883-63-3 Usage

Chemical Properties

White solid

Uses

suzuki reaction

Check Digit Verification of cas no

The CAS Registry Mumber 175883-63-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,5,8,8 and 3 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 175883-63:
(8*1)+(7*7)+(6*5)+(5*8)+(4*8)+(3*3)+(2*6)+(1*3)=183
183 % 10 = 3
So 175883-63-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H8BClO2/c1-5-2-3-6(8(10)11)4-7(5)9/h2-4,10-11H,1H3

175883-63-3 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (C2525)  3-Chloro-4-methylphenylboronic Acid (contains varying amounts of Anhydride)  

  • 175883-63-3

  • 1g

  • 290.00CNY

  • Detail
  • TCI America

  • (C2525)  3-Chloro-4-methylphenylboronic Acid (contains varying amounts of Anhydride)  

  • 175883-63-3

  • 5g

  • 940.00CNY

  • Detail
  • Alfa Aesar

  • (H28288)  3-Chloro-4-methylbenzeneboronic acid, 97%   

  • 175883-63-3

  • 1g

  • 494.0CNY

  • Detail
  • Alfa Aesar

  • (H28288)  3-Chloro-4-methylbenzeneboronic acid, 97%   

  • 175883-63-3

  • 5g

  • 1574.0CNY

  • Detail

175883-63-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Chloro-4-methylphenylboronic acid

1.2 Other means of identification

Product number -
Other names (3-Chloro-4-methylphenyl)boronic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:175883-63-3 SDS

175883-63-3Relevant articles and documents

Magnesium promoted autocatalytic dehydrogenation of amine borane complexes: A reliable, non-cryogenic, scalable access to boronic acids

Marciasini, Ludovic D.,Richard, Jimmy,Cacciuttolo, Bastien,Sartori, Guillaume,Birepinte, Melodie,Chabaud, Laurent,Pinet, Sandra,Pucheault, Mathieu

, p. 164 - 171 (2018/12/05)

Owing to the unusual reactivity of dialkylamine-borane complexes, a methodology was developed to simply access boronic acids. The intrinsic instability of magnesium aminoborohydride was tweaked into a tandem dehydrogenation borylation sequence. Proceeding via an autocatalytic cycle, amineborane dehydrogenation was induced by a variety of Grignard reagents. Overall, addition of the organomagnesium species onto specially designed dialkylamine-borane complexes led to a variety of boronic acids in high yields. In addition, the reaction can be performed under Barbier conditions, on a large scale.

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