176324-36-0Relevant articles and documents
Model insect antifeedants. Synthesis of azadiradione fragments through acyl radicals cyclizations and stannane coupling reactions
Fernandez-Mateos, Alfonso,Coca, Gustavo Pascual,Gonzalez, Rosa Rubio,Hernandez, Carolina Tapia
, p. 4817 - 4828 (2007/10/03)
A diastereoselective and versatile synthesis of the model insect antifeedant 16 related to azadiradione has been achieved in nine steps starting from α-cyclocitral 1. The key steps involve intramolecular alkene addition of an acyl radical and a Stille coupling reaction of a vinyl iodide with a stannylfuran.