176324-37-1

Basic information

• Product Name: 3-(2,6,6-trimethyl-2-cyclohexenyl)propanal
• Synonyms: 3-(2,6,6-trimethyl-2-cyclohexenyl)propanal
• CAS NO: 176324-37-1
• Molecular Weight: 180.29
• Mol File: 176324-37-1.mol

Chemical Properties

• CAS DataBase Reference: 3-(2,6,6-trimethyl-2-cyclohexenyl)propanal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2,6,6-trimethyl-2-cyclohexenyl)propanal(176324-37-1)
• EPA Substance Registry System: 3-(2,6,6-trimethyl-2-cyclohexenyl)propanal(176324-37-1)

Safety Data

• Hazardous Substances Data: 176324-37-1(Hazardous Substances Data)

Upstream product

• 176324-33-7 ethyl 2-ethoxycarbonyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-propanoate 
• 6627-74-3 (+/-)-α-cyclogeraniol 
• 176324-34-8 ethyl 3-(2,6,6-trimethyl-2-cyclohexenyl)-propanoate 
• 126456-65-3 ethyl 3-(2,6,6-trimethyl-2-cyclohexenyl)-2-propenoate 
• 14505-74-9 α-cyclocitral 
• 108878-63-3 3-(2,6,6-trimethyl-2-cyclohexenyl)propanol 
• 176324-45-1 3-(2,6,6-Trimethyl-cyclohex-2-enyl)-selenopropionic acid Se-phenyl ester 
• 176324-36-0 3-(2,6,6-Trimethyl-cyclohex-2-enyl)-selenopropionic acid Se-methyl ester 
• 24739-70-6 cyclogeranyl p-toluenesulfonate 

Downstream Products

• 728944-71-6 (3aSR,7RS,7aSR)-7-hydroxy-4,4,7a-trimethyl-octahydro-inden-1-one 
• 728944-77-2 (3aS,7S,7aS)-7-Hydroxy-4,4,7a-trimethyl-octahydro-inden-1-one 
• 1390627-41-4 (E)-ethyl 5-(2,6,6-trimethylcyclohex-2-enyl)-pent-2-enoate 
• 36772-07-3 6-but-3-enyl-1,5,5-trimethyl-cyclohexene 

Relevant articles and documents

Model insect antifeedants. Synthesis of azadiradione fragments through acyl radicals cyclizations and stannane coupling reactions

A diastereoselective and versatile synthesis of the model insect antifeedant 16 related to azadiradione has been achieved in nine steps starting from α-cyclocitral 1. The key steps involve intramolecular alkene addition of an acyl radical and a Stille coupling reaction of a vinyl iodide with a stannylfuran.

Synthesis of a CDE fragment of the insect antifeedant 12-hydroxyazadiradione

A diastereoselective and versatile synthesis of the model insect antifeedant 23 related to 12-hydroxyazadiradione has been achieved in 11 steps starting from α-cyclocitral, 1. The key steps involve intramolecular 1,3-dipolar cycloaddition of a nitrile oxide and a Stille coupling reaction of a vinyl iodide with a stannylfuran.