17651-00-2

Basic information

• Product Name: Benzene, (2-chlorocyclopropyl)-, trans-
• CAS NO: 17651-00-2
• Molecular Formula: C9H9Cl
• Molecular Weight: 152.623
• Mol File: 17651-00-2.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, (2-chlorocyclopropyl)-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-chlorocyclopropyl)-, trans-(17651-00-2)
• EPA Substance Registry System: Benzene, (2-chlorocyclopropyl)-, trans-(17651-00-2)

Safety Data

• Hazardous Substances Data: 17651-00-2(Hazardous Substances Data)

Upstream product

• 2415-80-7 1,1-dichloro-2-phenylcyclopropane 
• 3234-51-3 1,1-dibromo-2-phenylcyclopropane 
• 67-63-0 isopropyl alcohol 
• 100-42-5 styrene 
• 638-73-3 chlorodiiodomethane 
• 110889-04-8 (3-bromo-3,3-difluoroprop-1-yn-1-yl)triethylsilane 
• 2350-89-2 p-vinylbiphenyl 
• 23020-18-0 (1S,2R)-2-phenylcyclopropanecarboxylic acid 

Downstream Products

• 78072-76-1 p-(trans-2-Chlorocyclopropyl)acetophenone 
• 78072-86-3 1-((1S,2R)-2-Chloro-cyclopropyl)-4-(1-chloro-1-methyl-ethyl)-benzene 
• 78072-81-8 1-((1S,2R)-2-Chloro-cyclopropyl)-4-isopropenyl-benzene 
• 70328-37-9 p-(trans-2-Chlorocyclopropyl)nitrobenzene 

Relevant articles and documents

Photoinduced reduction of gem-dichlorocyclopropanes with SmI2 and benzenethiol

Upon irradiation with visible light, gem-dichlorocyclopropanes undergo reductive dechlorination with samarium diiodide and benzenethiol to provide the corresponding cyclopropanes in good yields. The reaction may proceed via the hydrogen abstraction from PhSH by cyclopropyl radicals formed in situ by the reduction with SmI2.

Dimethylation and Hydrodechlorination of gem-Dichlorocyclopropanes with Grignard Reagents Promoted by Fe(III) or Co(II) Catalyst

Reactions of gem-dichlorocyclopropanes with MeMgBr or t-BuMgCl were examined in the presence of Fe, Co, and Ni (group VIIIA, first transition series) catalysts.The Fe(dbm)3 catalyst promoted dimethylations of gem-dichlorocyclopropanes in the presence of 4

A simple and efficient hydrodehalogenation of 1,1-dihalocyclopropanes

1,1-Dibromo- and 1,1-dichlorocyclopropanes are converted into the corresponding monohalocyclopropanes (as mixtures of stereoisomers where appropriate) by reaction with 1.2-1.3 mol. equiv. of ethyl magnesium bromide and a small amount of titanium isopropoxide in ether. In the presence of an excess of ethylmagnesium bromide the product from the dibromide is the non- halogenated cyclopropane. Copyright (C) 1996 Elsevier Science Ltd.