1767-80-2Relevant academic research and scientific papers
Chemistry of decamethylsilicocene: oxidative addition of compounds with X-H bonds (X = F, Cl, Br, O, S)
Jutzi, Peter,Bunte, Ernst-August,Holtmann, Udo,Neumann, Beate,Stammler, Hans-Georg
, p. 139 - 147 (1993)
In the reaction of decamethylsilicocene (1) with protic substrates HX, the corresponding oxidative addition products 2-9, 11, 12, and 15 of the type (?-Me5C5)2Si(H)X are formed in good yields.Reactions of the hydrogen halides HF, HCl, and HBr with 1 lead
Asymmetric Allylation of Carbonyl Compounds with Tartrate-Modified Chiral Allylic Tin Reagents
Yamada, Koji,Tozawa, Takashi,Nishida, Minoru,Mukaiyama, Teruaki
, p. 2301 - 2308 (2007/10/03)
Chiral allylating reagents, readily generated in situ from tin(II) catecholate [SnII(O2C6H4)], allyl halides, chiral dialkyl tartrates, and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), reacted smoothly with aldehydes or reactive ketones at - 78 °C in the presence of a catalytic amount of copper salts to afford the corresponding optically active homoallyl alcohols. Allylation of aromatic aldehydes and pyruvates by the present chiral tin reagents proceeded in high yields (81-99%) with high enantioselectivities (89-94%ee). In addition, both enantiomers of dimethyl citramalate were prepared from the allylation products of benzyl pyruvate.
The Direct Electrochemical Synthesis of Tin(II) Derivatives of Aromaitc 1,2-Diols, and a Study of their Oxidative Addition Reactions
Mabrouk, Hassan E.,Tuck, Dennis G.
, p. 2539 - 2544 (2007/10/02)
The electrochemical oxidation of anodic tin in non-aqueous solutions of aromatic diols R(OH)2 (= 1,2-dihydroxybenzene, 2,3-dihydroxynaphthalene, tetrabromo-1,2-dihydroxybenzene, or 2,2'-dihydroxybiphenyl) gives rise to Sn(O2R) species in high yield.When 1
