Chemistry of decamethylsilicocene: oxidative addition of compounds with X-H bonds (X = F, Cl, Br, O, S)

DOI: 10.1016/0022-328X(93)80046-E

Source and publish data:

Journal of Organometallic Chemistry p. 139 - 147 (1993)

Update date:2022-08-03

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Authors:

Jutzi, Peter

Bunte, Ernst-August

Holtmann, Udo

Neumann, Beate

Stammler, Hans-Georg

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Article abstract of DOI:10.1016/0022-328X(93)80046-E

In the reaction of decamethylsilicocene (1) with protic substrates HX, the corresponding oxidative addition products 2-9, 11, 12, and 15 of the type (?-Me5C5)2Si(H)X are formed in good yields.Reactions of the hydrogen halides HF, HCl, and HBr with 1 lead

Full text of DOI:10.1016/0022-328X(93)80046-E

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