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311-46-6

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311-46-6 Usage

Uses

Reactant for synthesis of: Non-nucleoside inhibitors of HCV polymerase NS5BNeuropeptide Y1 receptor antagonistsAlkenylcarboxylates from Horner-Wadsworth-Emmons reactionsReactant for: Enantioselective transfer hydrogenation for preparation of the C7-C14 fragment of ulapualide A Intramolecular Michael reactionsOlefination of peptidyl aldehydes with stabilized ylides

Check Digit Verification of cas no

The CAS Registry Mumber 311-46-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,1 and 1 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 311-46:
(5*3)+(4*1)+(3*1)+(2*4)+(1*6)=36
36 % 10 = 6
So 311-46-6 is a valid CAS Registry Number.
InChI:InChI=1/C6H13O5P/c1-4-11-5(7)6(2,3)12(8,9)10/h4H2,1-3H3,(H2,8,9,10)

311-46-6 Well-known Company Product Price

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  • TCI America

  • (E1160)  Ethyl Dimethylphosphonoacetate  >97.0%(GC)

  • 311-46-6

  • 25g

  • 780.00CNY

  • Detail
  • Sigma-Aldrich

  • (02610)  Ethyldimethylphosphonoacetate  technical, ≥90% (GC)

  • 311-46-6

  • 02610-10ML

  • 1,175.85CNY

  • Detail

311-46-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name Ethyl dimethylphosphonoacetate

1.2 Other means of identification

Product number -
Other names Ethyl Dimethylphosphonoacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:311-46-6 SDS

311-46-6Relevant articles and documents

Alkyl phosphonate preparing method

-

Paragraph 0068; 0069; 0070; 0071, (2017/10/07)

The invention provides an alkyl phosphonate preparing method. The method comprises: performing an Arbuzov reaction on compound A and compound B in a continuous reaction apparatus, and continuously discharging the product obtained from the reaction from the continuous reaction apparatus during the reaction procedure, to obtain alkyl phosphonate. The reaction temperature in the reaction procedure is T1; either of compound A and compound B having a lower boiling point has a boiling point at a standard atmosphere pressure to be T2; T1 is higher than T2 by 10-40 DEG C; and the reaction pressure in the reaction procedure is 0.5-2.0 MPa. The preparing method in the invention may use halohydrocarbon having large steric hindrance and lower polarizability of carbon-halogen bond as compound A, thereby effectively expanding a selection range of substrate, and correspondingly expanding the types of alkyl phosphonate prepared by using the Arbuzov reaction.

A facile synthesis of novel chiral phosphonoacetates bearing a stereogenic phosphorus atom

Sano, Shigeki,Kujime, Eiko,Takemoto, Yuka,Shiro, Motoo,Nagao, Yoshimitsu

, p. 131 - 134 (2007/10/03)

Novel chiral phosphonoacetates bearing a stereogenic phosphorus atom were successfully synthesized by enzyme-catalyzed kinetic resolution of racemic phosphonoacetates.

Intramolecular cyclopropanation reactions en route to novel P- heterocycles

Hanson, Paul R.,Sprott, Kevin T.,Wrobleski, Aaron D.

, p. 1455 - 1458 (2007/10/03)

The first examples of intramolecular cyclopropanation reactions on a phosphonate template catalyzed by Rh2(OAc)4 are described. These reactions proceed in excellent yield and give mixtures of the P-heterocycles cis-2a-d and trans-2a-d with moderate levels of diastereoselectivity. The diastereoselectivity of this transformation is dependent upon the size of the alkyl group R contained in the alkyl α-diazodiallylphosphonoacetate starting materials 1a-d.

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