177271-87-3Relevant academic research and scientific papers
Synthesis and structure of 1,3-dienolate (CH2C(O)CH=CH2) complex of dipalladium(I) moiety: Contribution of π-olefin co-ordination of enolate to transition metal
Murahashi, Tetsuro,Kurosawa, Hideo
, p. 142 - 147 (1999)
1,3-Dienolate dipalladium(I) complex [{μ-CH2C(O)CH=CH2}Pd2(PPh3) 2(μ-Cl)] (2) is prepared and characterized. Complex 2 is easily protonated to yield 2-hydroxy-1,3-butadiene dipalladium(I) complex [{(μ
Rational synthesis of anionic, neutral and cationic palladium(I) dinuclear complexes containing bridging conjugated dienes
Murahashi, Tetsuro,Kanehisa, Nobuko,Kai, Yasushi,Otani, Toshiaki,Kurosawa, Hideo
, p. 825 - 826 (2007/10/03)
Addition of conjugated diene to an equimolar mixture of palladium(II) halides and a palladium(0) complex induces facile Pd-Pd bond formation to give anionic, neutral and cationic PdI-PdI dinuclear complexes containing bridging 1,3-diene ligands.
