178170-08-6Relevant academic research and scientific papers
Charge-based and charge-free molecular assemblies comprising π-extended derivatives of anion-responsive acyclic oligopyrroles
Bando, Yuya,Sakamoto, Shohei,Yamada, Ippei,Haketa, Yohei,Maeda, Hiromitsu
supporting information; experimental part, p. 2301 - 2303 (2012/05/04)
Assemblies comprising anion complexes of π-extended oligopyrrole derivatives and counter cations, as well as those of anion-free receptor molecules, exhibited the formation of mesophases based on columnar structures using electrostatic and π-π interactions. The Royal Society of Chemistry.
A new route to porphyrins substituted with long alkoxy groups, attempts to prepare the discotic liquid crystals
Murashima, Takashi,Wakamori, Naoko,Uchihara, Yuki,Ogawa, Takujl,Uno, Hidemitsu,Ono, Noboru
, p. 165 - 171 (2007/10/03)
Pyrroles substituted with long alkoxy groups are prepared by the reaction of iminodiacetic acid dimethyl ester and dimethyl oxalate and the subsequent alkylation. These pyrroles are good precursor molecules for the corresponding porphyrins, which are expected to form an ordered columnar mesophase and are able to co-ordinate to various metals.
