17878-30-7

Upstream product

• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 120-83-2 2,4-dichlorophenol 
• 75-79-6 Methyltrichlorosilane 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 17864-01-6 2,4-bis(trimethylsilyl)phenyl trimethylsilyl ether 
• 844856-45-7 ZrCl(2,4-pentanedionato)2(OC₆H₃Cl₂-2,4) 
• 844856-51-5 Zr(2,4-pentanedionato)2(OC₆H₃Cl₂-2,4)2 
• 1356497-05-6 (3,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)trimethylsilane 
• 1356496-95-1 (3-benzyloxy-3',4'-diphenyl)diphenylacetylene 
• 185995-59-9 1-(3-hydroxyphenyl)-2-(3,4-diphenylphenyl)ethane 
• 185994-78-9 methyl 2-{3-[2-(3,4-diphenylphenyl)ethan-1-yl]phenoxy}acetate 
• 186835-06-3 3-(3,4-diphenylphenyl)propan-1-ol 
• 420-56-4 trimethylsilyl fluoride 
• 32848-21-8 Perfluorbutylsulfonsaeure-2,4-dichlor-phenylester 
• 41605-69-0 2,4-dichlorophenyl trifluoromethanesulfonate 
• 120-83-2 2,4-dichlorophenol 

Relevant academic research and scientific papers

Nanomagnetic zirconia-based sulfonic acid (Fe3O4@ZrO2-Pr-SO3H): A new, efficient and recyclable solid acid catalyst for the protection of alcohols: Via HMDS under solvent free conditions

In the present work, sulfonic acid functionalized nanomagnetic zirconia is prepared by the reaction of (3-mercaptopropyl)trimethoxysilane and nanomagnetic zirconia. Then, nanomagnetic zirconia-based sulfonic acid (Fe3O4@ZrO2/su

Magnetic nanoparticle-supported DABCO tribromide: A versatile nanocatalyst for the synthesis of quinazolinones and benzimidazoles and protection/deprotection of hydroxyl groups

1,4-Diazabicyclo[2.2.2]octane tribromide supported on magnetic Fe3O4 nanoparticles (MNPs-DABCO tribromide) as a novel heterogeneous tribromide type compound was found to be an efficient and reusable nanocatalyst for the one-pot synthesis of 2-arylquinazolin-4(3H)-ones and 2-aryl-1H-benzo[d]imidazoles through oxidative cyclization of aldehydes with 2-aminobenzamides and 1,2-phenylenediamine, respectively. Also, MNPs-DABCO tribromide catalyzed trimethylsilylation/tetrahydropyranylation and desilylation/depyranylation of a wide variety of alcohols and phenols through changing the solvent medium at room temperature.

Nano Fe3O4@ZrO2/SO42?: A highly efficient catalyst for the protection and deprotection of hydroxyl groups using HMDS under solvent-free condition

In this work, we introduce a new procedure for the protection and deprotection process of various types of alcohols and phenols by HMDS in the presence of nano magnetic sulfated zirconia (Fe3O4@ZrO2/SO42?) as a solid acid catalyst under very mild and solvent-free condition. This method has interesting advantages like short reaction times and a simple workup process. With regard to some outstanding benefits of this new heterogeneous catalyst such as excellent yield, reusability of the catalyst and easy thermal stability, high acidity, strong and excellent magnetic properties, this method can be very interesting in aspect of green chemistry Principles.

2-(Trimethylsilyl)phenyl Trimethylsilyl Ethers as Stable and Readily Accessible Benzyne Precursors

Stable 2-(trimethylsilyl)phenyl trimethylsilyl ethers, readily obtained from the corresponding halogenated phenols in two steps, were identified as novel benzyne precursors. These species were converted to benzynes by a domino reaction of O-desilylation,

Tributyltin grafted onto the surface of 3-aminopropyl functionalized γ-Fe2O3 nanoparticles: A magnetically-recoverable catalyst for trimethylsilylation of alcohols and phenols

Bonding of a homogenous tributyltin chloride catalyst on the surface of functionalized magnetic nanoparticles provides a new stable, efficient and magnetically recyclable catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazan un

Alum: An efficient catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane

A highly convenient method for the trimethylsilylation of alcohols and phenols via treatment by hexamethyldisilazane in the presence of alum as a catalyst has been developed. A wide variety of hydroxyl groups were selectively protected in CH3CN under mild conditions.

Copper-catalyzed borylation reactions of alkynes and arynes

One, two, three, four: A copper(I)-phosphine complex catalyzes the diborylation of alkynes and arynes, and the tri- or tetraborylation of propargyl ethers (see scheme; pin=pinacolato). In the latter cases, the C-O bond(s) as well as the C≡C bond are borylated in one pot. Furthermore, a diborylation product serves as an intermediate in the efficient synthesis of ortho-terphenyls with pharmacological activity.

Fe(HSO4)3 promoted trimethylsilylation of alcohols and phenols in solution and under solvent-free conditions

Alcohols and phenols are efficiently converted to their corresponding trimethylsilyl ethers with hexamethyldisilazane (HMDS) in the presence of Fe(HSO4)3 in solution and under solvent-free conditions.

An Efficient and Highly Chemoselective Method to Desilylate Silyl Ethers

An efficient and highly chemoselective desilylating method is described.Trimethylsilyl ethers (0.25 M) in a CH3OH/CCl4 (1:1) solvent mixture are deprotected to their corresponding alcohols with ultrasound in a commercial ultrasonic cleaning bath.Selective deprotection of tert-butyldimethylsilyl ethers of benzyl alcohols and phenols is achieved under ultrasonic conditions.We deprotected also tert-butyldimethylsilyl ethers of primary alcohols, whereas tert-butyldimethylsilyl ethers of secondary and tertiary alcohols are stable under these conditions. - Key words: Sonochemistry; Ultrasound; Cavitation; Desilylation; Chemoselection; Deprotection.