17931-24-7

Basic information

• Product Name: Naphtho[2,1-d]thiazol-2(3H)-one (9CI)
• Synonyms: Naphtho[2,1-d]thiazol-2(3H)-one (9CI)
• CAS NO: 17931-24-7
• Molecular Formula: C11H7NOS
• Molecular Weight: 201.24438
• Product Categories: BENZOTHIAZOLE
• Mol File: 17931-24-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Naphtho[2,1-d]thiazol-2(3H)-one (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Naphtho[2,1-d]thiazol-2(3H)-one (9CI)(17931-24-7)
• EPA Substance Registry System: Naphtho[2,1-d]thiazol-2(3H)-one (9CI)(17931-24-7)

Safety Data

• Hazardous Substances Data: 17931-24-7(Hazardous Substances Data)

Upstream product

• 1166-32-1 N,N'-di(2-naphthyl)thiourea 
• 124-38-9 carbon dioxide 
• 53338-20-8 2-aminonaphthalene-1-thiol 
• 454713-45-2 naphthalen-2-yl-carbamic acid tert-butyl ester 
• 91-59-8 naphthalen-2-ylamine 
• 1636-33-5 2-naphthyl isothiocyanate 
• 57-13-6 urea 
• 17931-25-8 2-chloronaphtho<2,1-d>thiazole 

Downstream Products

• 17931-25-8 2-chloronaphtho<2,1-d>thiazole 

Relevant articles and documents

Transition-metal-free synthesis of thiazolidin-2-ones and 1,3-thiazinan-2-ones from arylamines, elemental sulfur and CO2

Transfering waste to treasure is highly important in green chemistry. However, it is difficult to realize it efficiently due to the low reactivity, especially the simultaneous utilization of two unreactive feedstocks in one reaction. Herein, we report the first utilization of both elemental sulfur and CO2 in a multi-component reaction to generate valuable thiazolidin-2-ones and 1,3-thiazinan-2-ones. Under transition-metal-free reaction conditions, a variety of easily available arylamines react with elemental sulfur and CO2 (1 atm) to give functional thiazolidin-2-ones and 1,3-thiazinan-2-ones in moderate to good yields via C-H bond functionalization. This strategy is highlighted by high step economy with generation of three bonds in one reaction and good functional groups tolerance.