17933-10-7Relevant articles and documents
Haubold,Weidlein
, p. 251,255, 259 (1976)
Novel Organoboron-Oxygen-Halogenaluminium Compounds from Triorganoboroxins with Aluminium Trihalides
Koester, Roland,Angermund, Klaus,Serwatowski, Janusz,Sporzynski, Andrzej
, p. 1301 - 1314 (2007/10/02)
4 mol of triorganoboroxins (RBO)3 (1) react with 6 mol of aluminium trihalides AlHal3 (2) under cleavage of 4 mol dihalogenoorganoboranes RBHal2 (3) leading in high yields to 2 mol of compounds 4 having the composition R4Al3B4Hal5O6 (MS analyses) .The structure of 4aa, 4ba, 4ca, and 4bb in solution is deduced from spectroscopic data (IR; 1H, 11B, 17O and 27Al NMR).The molecular structure of the solid (C6H5)4Al3B4Cl5O6 (4da) with two (AlOBOBO)-rings bonded through one penta-coordinated aluminium atom was determined by X-ray diffraction analysis.