179469-95-5

Upstream product

• 179470-10-1 6,7-Dihydroxy-1,4-dimethoxynaphthalene 
• 207279-92-3 6,7-Bis-benzyloxy-1,4-dimethoxy-naphthalene 
• 179469-93-3 6-(tert-Butyl-dimethyl-silanyloxy)-7-[(Z)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-1,4-dimethoxy-naphthalene 
• 179469-92-2 (3-Allyl-5,8-dimethoxy-naphthalen-2-yloxy)-tert-butyl-dimethyl-silane 
• 13575-75-2 6,7-dimethoxy-1-oxo-1,2,3,4-tetrahydronaphthalene 
• 1027937-03-6 3-[(Z)-6-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-5,8-dimethoxy-naphthalen-2-ol 
• 207280-38-4 tert-Butyl-((Z)-3-methyl-hexa-2,5-dienyloxy)-diphenyl-silane 
• 151950-84-4 (Z)-tert-butyl((3-iodobut-2-en-1-yl)oxy)diphenylsilane 
• 179470-11-2 Trifluoro-methanesulfonic acid 5,8-dimethoxy-3-trifluoromethanesulfonyloxy-naphthalen-2-yl ester 
• 179469-94-4 Trifluoro-methanesulfonic acid 3-[(Z)-6-(tert-butyl-diphenyl-silanyloxy)-4-methyl-hex-4-enyl]-5,8-dimethoxy-naphthalen-2-yl ester 
• 179469-91-1 Trifluoro-methanesulfonic acid 3-(tert-butyl-dimethyl-silanyloxy)-5,8-dimethoxy-naphthalen-2-yl ester 

Downstream Products

• 179469-98-8 (1S)-1-(2-Hydroxyethyl)-5,8-dimethoxy-1-methyl-1,2,3,4-tetrahydroanthracene 

Relevant academic research and scientific papers

Synthesis and evaluation of a new chiral arsine ligand; 2,2'-bis(diphenylarsino)-1,1'-binaphthyl (BINAs)

Chiral 2,2'-bis(diphenylarsino)-1,1'-binaphthyl (BINAs) was synthesized and found to be an effective ligand in an alkenyl iodide-using intramolecular asymmetric Heck reaction.

Catalytic asymmetric synthesis of halenaquinone and halenaquinol

A catalytic asymmetric synthesis of halenaquinone (1) and halenaquinol (2) has been achieved using an asymmetric Heck reaction or a cascade Suzuki cross-coupling and an asymmetric Heck reaction as a key step. This synthesis also features the one-pot construction of a unique pentacyclic ring system from a tricyclic system using palladium chemistry. Moreover, the use of Ph3As as an achiral ligand has been found to enhance both the cascade Suzuki cross-coupling and also the Heck reaction to a synthetically useful extent.