1797-75-7

Basic information

• Product Name: DIALLYL MALONATE
• Synonyms: DIALLYL MALONATE;diprop-2-enyl propanedioate
• CAS NO: 1797-75-7
• Molecular Formula: C₉H₁₂O₄
• Molecular Weight: 184.19
• Product Categories: monomer
• Mol File: 1797-75-7.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 110-112°C 9mm
• Flash Point: 107.8 °C
• Appearance: /
• Density: 1.057 g/cm³
• Vapor Pressure: 0.0557mmHg at 25°C
• Refractive Index: 1.449
• CAS DataBase Reference: DIALLYL MALONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIALLYL MALONATE(1797-75-7)
• EPA Substance Registry System: DIALLYL MALONATE(1797-75-7)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 1797-75-7(Hazardous Substances Data)

Usage

General Description

Diallyl malonate is a chemical compound that is used in various industrial applications. It is a clear, colorless liquid with a pungent odor, and it is highly flammable. Diallyl malonate is primarily used as a monomer in the production of polymers and resins, where it serves as a crosslinking agent for enhanced durability and strength. It is also used as a chemical intermediate in the production of pharmaceuticals, as well as in the synthesis of perfumes and fragrances. Additionally, it can be used as a flavoring agent in food products, although its use in this application is limited due to its potentially toxic properties. Diallyl malonate should be handled and stored with care, as it can be hazardous to human health and the environment.

InChI:InChI=1/C9H12O4/c1-3-5-12-8(10)7-9(11)13-6-4-2/h3-4H,1-2,5-7H2

Upstream product

• 205114-96-1 2-Bromo-malonic acid allyl ester methyl ester 
• 107-18-6 allyl alcohol 
• 1663-67-8 malonoyl dichloride 
• 2033-24-1 cycl-isopropylidene malonate 
• 141-82-2 malonic acid 
• 106-95-6 allyl bromide 
• 16854-72-1 Dithiomalonsaeure-S,S'-diphenylester 
• 141-95-7 sodium malonate 
• 107-05-1 3-chloroprop-1-ene 
• 868-26-8 dimethyl 2-bromomalonate 
• 108-59-8 malonic acid dimethyl ester 
• 504-64-3 carbon suboxide 

Downstream Products

• 1027542-25-1 (S)-2-Allyloxycarbonyl-3-((S)-3-tert-butoxycarbonylamino-4,4-dimethyl-2-oxo-pentyl)-succinic acid 1-allyl ester 4-benzyl ester 
• 249588-49-6 2-[2-(tert-butyl-dimethyl-silanyloxy)-3-tritylsulfanyl-propyl]-malonic acid diallyl ester 
• 930101-15-8 diallyl 2-(2-nitrophenyl)malonate 
• 934738-39-3 diallyl 2-[2-(4-methoxycarbonylphenyl)ethyl]malonate 
• 934810-06-7 Diallyl [4-(tert-butoxycarbonyl)benzyl]malonate 
• 1168-85-0 Di-(3-cyclohexylpropyl)-malonat 
• 52505-39-2 diallyl 2-benzylidenemalonate 
• 84646-68-4 Dimethyl 3-cyclopentene-1,1-dicarboxylate 
• 934753-56-7 diallyl 2-(4-cyanobutyl)-2-[2-(4-methoxycarbonylphenyl)ethyl]malonate 
• 1402592-36-2 1,3-allyl 2-(diphenylsulfuranylidene)malonate 

Relevant articles and documents

Ball-Milling-Enabled Reactivity of Manganese Metal**

Efforts to generate organomanganese reagents under ball-milling conditions have led to the serendipitous discovery that manganese metal can mediate the reductive dimerization of arylidene malonates. The newly uncovered process has been optimized and its mechanism explored using CV measurements, radical trapping experiments, EPR spectroscopy, and solution control reactions. This unique reactivity can also be translated to solution whereupon pre-milling of the manganese is required.

Synthesis and structure of allylated derivatives of fullerenes C60 and C70

New chromatographically pure monoand hexamethanofullerenes C60 and C70 containing active allylic groups were synthesized by Bingel—Hirsch reaction. These compounds are promising for the studies of biological activity, as well as for obtaining on their basis new fullerenecontaining materials. The purity and composition of the synthesized compounds were confirmed by MALDI-TOF mass spectrometry and HPLC, their structure was established by 1H and 13C NMR spectroscopy and X-ray diffraction.

A highly-ordered 3D covalent fullerene framework

A highly-ordered 3D covalent fullerene framework is presented with a structure based on octahedrally functionalized fullerene building blocks in which every fullerene is separated from the next by six functional groups and whose mesoporosity is controlled by cooperative self-assembly with a liquid-crystalline block copolymer. The new fullerene-framework material was obtained in the form of supported films by spin coating the synthesis solution directly on glass or silicon substrates, followed by a heat treatment. The fullerene building blocks coassemble with a liquid-crystalline block copolymer to produce a highly ordered covalent fullerene framework with orthorhombic Fmmm symmetry, accessible 7.5 nm pores, and high surface area, as revealed by gas adsorption, NMR spectroscopy, small-angle X-ray scattering (SAXS), and TEM. We also note that the 3D covalent fullerene framework exhibits a dielectric constant significantly lower than that of the nonporous precursor material. Self-assembling C60: A highly ordered 3D fullerene framework is prepared with a structure based on octahedrally functionalized fullerene building blocks. The C60 building blocks coassemble with a liquid-crystalline block copolymer to produce a covalent fullerene framework with orthorhombic Fmmm symmetry and 7.5 nm pores.