17983-40-3Relevant academic research and scientific papers
Cyanosilylation of benzaldehyde with TMSCN over perovskite-type oxide catalyst prepared by thermal decomposition of heteronuclear cyano complex precursors
Yamaguchi, Syuhei,Okuwa, Takahisa,Wada, Hiroki,Yamaura, Hiroyuki,Yahiro, Hidenori
, p. 9551 - 9560 (2015)
The perovskite-type oxide catalyst, SmFeO3, prepared by decomposition method of heteronuclear cyano complex precursor (CN method) was applied to liquid-phase organic reaction, cyanosilylation of benzaldehyde with TMSCN. The maximum catalytic ac
Hybrid dimers based on metal-substituted Keggin polyoxometalates (metal = Ti, Ln) for cyanosilylation catalysis
An, Haiyan,Zhang, Yumeng,Hou, Yujiao,Hu, Tao,Yang, Wei,Chang, Shenzhen,Zhang, Jianjun
, p. 9079 - 9089 (2018)
Six novel organic-inorganic hybrid polyoxometalate derivatives, K[(H2O)4(3-Hpic)2Ce][(H2O)5(3-Hpic)2Ce][PW10Ti2O40]·11H2O 1, K[(H2O)s
Transformation of α-assisted carbanions into the corresponding trimethylsiloxy derivatives using bis(trimethylsilyl)peroxide
Dembech,Guerrini,Ricci,Seconi,Taddei
, p. 2999 - 3006 (2007/10/02)
The reaction of bis(trimethylsilyl)peroxide with tlithium derivatives of sulphides and nitriles is reported to give the corresponding O-trimethylsilyl hemithioacetals and cyanohydrins. From these products the carbonyl function can be exposed in acidic media or in the presence of fluoride ions. This methodology provides an attractive route to transform a CH2-X group (X = PhS, MeS or CN) into the corresponding CHO, allowing the preparation of aldehydes that can be considered difficult to prepare such as, for example, formyltrimethylsilane which was generated and trapped in situ using a Wittig reaction.
Preparation of sulfines by alkylidenation of sulfur dioxide using α-silyl carbanions
Porskamp, P. A. T. W.,Leij, M. van der,Lammerink, B. H. M.,Zwanenburg, B.
, p. 400 - 404 (2007/10/02)
The synthesis of sulfines 4 from a series of active methylene compounds is described.Deprotonation, followed by silylation, gives the trimethylsilyl compounds 2.Subsequent deprotonation to α-silyl carbanions and treatment with an excess of sulfur dioxide
