18042-35-8

Basic information

• Product Name: 2-Butanone, 4-(dimethylphenylsilyl)-
• CAS NO: 18042-35-8
• Molecular Formula: C12H18OSi
• Molecular Weight: 206.36
• Mol File: 18042-35-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 4-(dimethylphenylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 4-(dimethylphenylsilyl)-(18042-35-8)
• EPA Substance Registry System: 2-Butanone, 4-(dimethylphenylsilyl)-(18042-35-8)

Safety Data

• Hazardous Substances Data: 18042-35-8(Hazardous Substances Data)

Upstream product

• 17983-34-5 3-(dimethyl(phenyl)silyl)propionyl chloride 
• 506-82-1 dimethylcadmium 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 78-94-4 methyl vinyl ketone 
• 768-33-2 phenyldimethylsilyl chloride 
• 766-77-8 Dimethylphenylsilane 
• 1833-51-8 chloromethyldimethylphenylsilane 
• 17932-70-6 [(dimethyl-phenyl-silanyl)-methyl]-malonic acid diethyl ester 
• 18192-31-9 ethyl 3-(dimethylphenylsilyl)propionate 
• 17872-96-7 3-[(dimethyl)phenylsilyl]propionic acid 
• 769-00-6 (iodomethyl)dimethylphenylsilane 
• 57519-88-7 1,1-dichloro-1-phenyl-2,2,2-trimethyldisilane 
• 1145-98-8 1,2-diphenyltetramethyldisilane 

Downstream Products

• 18410-34-9 3-(dimethylphenylsilyl)-1,1-dimethyl-1-propanol 
• 109023-17-8 [Dimethyl-(3-trimethylsilanyloxy-but-3-enyl)-silanyl]-benzene 

Relevant articles and documents

Visible-Light-Mediated Metal-Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si?H Activation

Although there has been significant progress in the development of transition-metal-catalyzed hydrosilylations of alkenes over the past several decades, metal-free hydrosilylation is still rare and highly desirable. Herein, we report a convenient visible-

Palladium/Me3SiOTf-catalyzed bis-silylation of α,β-unsaturated carbonyl compounds without involving oxidative addition of disilane

In the presence of a catalytic amount of Me3SiOTf and palladium(0), the addition of disilane to α,β-unsaturated carbonyl compounds proceeds under very mild conditions via η3-siloxyallylpalladium generated by the reaction of enone, en

Conjugate addition of silyl groups to β-unsubstituted enones, and Si-to-OH conversion: A synthesis of (±)-lavandulol

TMS chloride raises the yield in the conjugate addition of silylcuprates and zincates to β-unsubstituted enones, and Si-to-OH conversion is possible using the 2-methylbut-2-enyl(diphenyl)silyl group in the presence of highly nucleophilic alkenes. Both reactions are used in a synthesis of lavandulol.