1809-05-8

Basic information

• Product Name: 3-IODOPENTANE
• Synonyms: 3-IODOPENTANE;1-Ethylpropyl iodide
• CAS NO: 1809-05-8
• Molecular Formula: C₅H₁₁I
• Molecular Weight: 198.05
• EINECS: 217-313-5
• Mol File: 1809-05-8.mol
• Article Data: 9

Chemical Properties

• Melting Point: -85.6°C (estimate)
• Boiling Point: 154.22°C (estimate)
• Flash Point: 44.6 °C
• Appearance: /
• Density: 1.5047
• Vapor Pressure: 5.82mmHg at 25°C
• Refractive Index: 1.4952
• CAS DataBase Reference: 3-IODOPENTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-IODOPENTANE(1809-05-8)
• EPA Substance Registry System: 3-IODOPENTANE(1809-05-8)

Safety Data

• Hazardous Substances Data: 1809-05-8(Hazardous Substances Data)

Usage

General Description

3-Iodopentane, also known as C5H11I, is a chemical compound that belongs to the class of organic compounds known as halogenated hydrocarbons. It is clear, colorless liquid primarily used in synthetic reactions and other chemical processes. It contains iodine, which is a halogen, attached to a pentane molecule. Its functional group is specifically categorized as an alkyl iodide. This substance can be hazardous if exposed to skin or if inhaled; appropriate safety measures should be observed while handling this chemical. Its molecular weight is about 214.04 g/mol.

InChI:InChI=1/C5H11I/c1-3-5(6)4-2/h5H,3-4H2,1-2H3

Upstream product

• 1191-96-4 ethylcyclopropane 
• 10034-85-2 hydrogen iodide 
• 6032-29-7 (+/-)-2-pentanol 
• 7553-56-2 iodine 
• 38011-62-0 3-pentyl diphenyl phosphinite 
• 74-88-4 methyl iodide 
• 109-66-0 pentane 
• 1809-15-0 bis(1-ethylpropyl)phosphonate 
• 584-02-1 2-pentanol 
• 26184-62-3 (S)-2-pentanol 

Downstream Products

• 88-09-5 2-Ethylbutanoic acid 
• 646-04-8 (E)-pent-2-ene 
• 1809-10-5 3-bromopentane 
• 109-66-0 pentane 
• 1105597-11-2 C₂₈H₄₈OSi 
• 1217437-01-8 (Rp,Rp)-1,2-bis[(o-(3-pentyloxy)phenyl)(phenyl)phosphino-P-borane]ethane 
• 73713-91-4 2-(1-ethylpropyl)-2-benzoxazole 
• 544-76-3 Hexadecane 
• 17312-58-2 3-ethylundecane 
• 111-66-0 oct-1-ene 
• 367252-68-4 (3R,4R,5S)-ethyl 4-acetamido-5-((tert-butoxycarbonyl)amino)-3-(pentan-3-yloxy)cyclohex-1-enecarboxylate 
• 17089-16-6 3-{3-[p-(1-Ethylpropyloxy)-phenyl]-propyl}-2-hydroxy-1,4-naphthochinon 
• 1196-58-3 (1-ethylpropyl)benzene 
• 748772-19-2 N'-[2-(1-ethyl-propoxy)-phenyl]-ethane-1,2-diamine 

Relevant articles and documents

NaIO4-KI-NaN3 as a new reagent system for C-H functionalization in hydrocarbons

The NaIO4-KI-NaN3 combination has been found to be an efficient, reliable, and inexpensive reagent system for mono- and 1,2-difunctionalization of hydrocarbons via C-H bond activation to afford vicinal azido- and acetoxy iodinations of cyclic hydrocarbons.

Direct bromination and iodination of non-activated alkanes by hypohalite reagents

The direct functionalisation of alkanes through bromination and iodination has been successfully achieved. The combination of stoichiometric mixtures of elemental halogen and sodium alkoxides leads to the formation of alkyl hypobromites and hypoiodites as reagents. The halogenation occurs without external photostimulation under thermal reaction conditions. Georg Thieme Verlag Stuttgart.

Mechanism of decomposition of quasiphosphonium intermediates: Borderline SN1 character of alkyl-oxygen fission in sec-alkyloxyphosphonium salts

Short-lived alkoxyphosphonium intermediates have been detected in the interactions of alkyl diphenylphosphinites ROPPh2 (R = Et, Pr i, Bu8, and 3-pentyl) with iodomethane at room temperature. Phosphorus chemical shifts for the sec-alkoxy(methyl) diphenylphosphonium iodides (δp 68.6-68.7 ppm) are at slightly higher field than for ethoxy(methyl)diphenylphosphonium iodide (δp 72.4 ppm), in accord with higher electron density at phosphorus in the secondary alkyl sytems. Relative rates of decomposition in CDCl3 (Me > Et > Pri ? neopentyl) are in accord with SN2-type cleavage of the R-O bond but within the secondary alkyl series the relative rates (Pri 8 N1 mechanism is proposed.