18102-32-4

Basic information

• Product Name: 4-Hydroxy-3-Methoxy-2-Methylbenzaldehyde
• Synonyms: 4-Hydroxy-3-Methoxy-2-Methylbenzaldehyde
• CAS NO: 18102-32-4
• Molecular Formula: C₉H₁₀O₃
• Molecular Weight: 166.1739
• Mol File: 18102-32-4.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Hydroxy-3-Methoxy-2-Methylbenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Hydroxy-3-Methoxy-2-Methylbenzaldehyde(18102-32-4)
• EPA Substance Registry System: 4-Hydroxy-3-Methoxy-2-Methylbenzaldehyde(18102-32-4)

Safety Data

• Hazardous Substances Data: 18102-32-4(Hazardous Substances Data)

Upstream product

• 5533-03-9 2-methoxy-4-methoxymethylphenol 
• 498-00-0 4-hydroxymethyl-2-methoxyphenol 
• 109685-13-4 4-hydroxy-3-methoxy-2-methylbenzyl methyl ether 
• 67-66-3 chloroform 
• 18102-31-3 2-methoxy-3-methylphenol 

Downstream Products

• 846543-14-4 4-hydroxy-3-methoxy-2-methyl-5-(1-methyl-allyl)-benzaldehyde 
• 103744-20-3 carbazomycinal 
• 141258-34-6 4-acetoxy-3-methoxy-2-methyl-6-nitrobenzaldehyde 
• 141278-65-1 4-hydroxy-3-methoxy-2-methyl-6-nitrobenzaldehyde 
• 141258-32-4 6-amino-4-hydroxy-3-methoxy-2-methylbenzaldehyde 
• 846543-19-9 6-[2-benzyloxy-3-methoxy-4-methyl-5-(toluene-4-sulfonyloxy)-phenyl]-2-methyl-3-oxo-heptanoic acid ethyl ester 
• 856190-62-0 6-[2-benzyloxy-3-methoxy-4-methyl-5-(toluene-4-sulfonyloxy)-phenyl]-3-oxo-heptanoic acid ethyl ester 
• 846543-18-8 toluene-4-sulfonic acid 4-benzyloxy-3-methoxy-2-methyl-5-(1-methyl-4-oxo-butyl)-phenyl ester 
• 846543-29-1 toluene-4-sulfonic acid 3-methoxy-4-methoxymethoxy-2-methyl-5-(1-methyl-pent-4-ynyl)-phenyl ester 
• 846543-17-7 toluene-4-sulfonic acid 4-benzyloxy-3-methoxy-2-methyl-5-(1-methyl-allyl)-phenyl ester 
• 846543-30-4 toluene-4-sulfonic acid 4-hydroxy-3-methoxy-2-methyl-5-(1-methyl-pent-4-ynyl)-phenyl ester 
• 846543-38-2 toluene-4-sulfonic acid 3-methoxy-4-methoxymethoxy-2-methyl-5-(1-methyl-4-oxo-butyl)-phenyl ester 
• 846543-37-1 toluene-4-sulfonic acid 3-methoxy-4-methoxymethoxy-2-methyl-5-(1-methyl-allyl)-phenyl ester 
• 846543-16-6 4-benzyloxy-3-methoxy-2-methyl-5-(1-methyl-allyl)-phenol 

Relevant articles and documents

A new method for the facile synthesis of hydroxylated flavones by using allyl protection

The iodine-induced oxidative cyclization of 2′-hydroxychalcones provides a simple, highly efficient approach to various hydroxy flavones and analogues. This process is run under mild conditions, tolerates various functional groups, and provides hydroxy flavones in good to excellent yield. The allyl-protected acetophenones and benzaldehydes were smoothly deallylated under similar conditions.

PROCESSES OF MAKING SESQUITERPENOID TASHIRONIN, ITS ANALOGS AND THEIR USES

The compound having the structure of the formula (genus of compound 1 excluding Tashironin or Debenzoyltashironin) wherein, R1 is H or Bz when no more than three of R8, R9, R10 and R11 are H, or R1 is Bn, (C1-C4) alkyl, or CF3; R2 is H, (C1-C4) aldyl, halide, OC(O) (C1-C4) alkyl, OC(O) Ph, or OCF3; R3 is p-toluene sulfonyloxy, methane sulfonyloxy, C(O) (C1-C4)alkyl, or OC(O) (C1-C4)alkyl, bond α is a single bond, and bond β is a double bond or R3 is O, bond α is a double bond and bond β is a single bond; R4 is H, I, Br, Cl, Si(CH3)3, (C1-C4)alkyl, or OCF3; R5 is OH, OSi (CH3)3, O(C1-C4)alkyl, or OCF3, and bond γ is a single bond, or R5 is O and bond γ is a double bond; R6 is H, (C1-C4) alkyl, or CF3.

TRANSITION METAL-DIENE COMPLEXES IN ORGANIC SYNTHESIS, PART 9. FIRST TOTAL SYNTHESIS OF CARBAZOMYCINAL

Using consecutive iron-induced C-C and C-N bond formation the first total synthesis of carbazomycinal (carbazomycin E) was accomplished.