181136-65-2

Basic information

• Product Name: Phenyl2,3,4-tri-O-acetyl-a-L-thiorhamnopyranoside
• Synonyms: Phenyl2,3,4-tri-O-acetyl-a-L-thiorhamnopyranoside
• CAS NO: 181136-65-2
• Molecular Formula: C₁₈H₂₂O₇S
• Molecular Weight: 0
• Mol File: 181136-65-2.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Phenyl2,3,4-tri-O-acetyl-a-L-thiorhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyl2,3,4-tri-O-acetyl-a-L-thiorhamnopyranoside(181136-65-2)
• EPA Substance Registry System: Phenyl2,3,4-tri-O-acetyl-a-L-thiorhamnopyranoside(181136-65-2)

Safety Data

• Hazardous Substances Data: 181136-65-2(Hazardous Substances Data)

Upstream product

• 75-36-5 acetyl chloride 
• 503065-75-6 phenyl 1-thio-6-deoxy-β-L-mannopyranoside 
• 7404-35-5 1,2,3,4-tetra-O-acetyl-L-rhamnopyranose 
• 930-69-8 sodium thiophenolate 
• 28915-80-2 2,3,4-tri-O-acetyl-L-rhamnopyranose 
• 108-98-5 thiophenol 
• 73-34-7 L-rhamnose 
• 108-24-7 acetic anhydride 
• 5158-64-5 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide 
• 3615-41-6 L-Rhamnose 

Downstream Products

• 1382229-04-0 C₁₉H₂₂O₆S₂ 
• 1382229-08-4 phenyl 2-O-sulfonylbenzyl-4-O-TIPS-1-thio-β-L-rhamnopyranoside 
• 1382229-12-0 phenyl 2-O-sulfonylbenzyl-3,4-di-O-TIPS-1-thio-β-L-rhamnopyranoside 
• 1382229-16-4 phenyl 2-O-sulfonylbenzyl-3-O-TBS-4-O-TIPS-1-thio-β-L-rhamnopyranoside 
• 1382230-17-2 C₃₄H₆₂O₇SSi₂ 
• 1382230-20-7 C₃₄H₆₂O₇SSi₂ 
• 1382230-29-6 C₅₆H₈₂O₁₂SSi₂ 
• 1382230-32-1 C₃₁H₅₆O₇SSi₂ 
• 1382230-35-4 C₃₁H₅₆O₇SSi₂ 
• 1382230-38-7 C₂₈H₄₈O₇SSi 
• 1382230-41-2 C₂₈H₄₈O₇SSi 
• 1382229-53-9 C₄₁H₄₈O₁₂S 
• 1569097-44-4 methyl (2,3,4-tri-O-acetyl-β-L-rhamnopyranosyl)-(1→6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 503065-99-4 1-adamantyl 4-O-benzoyl-3-O-benzyl-2-O-(2-trifluoromethylbenzenesulfonyl)-β-L-rhamnopyranoside 

Relevant articles and documents

Concise Synthesis of 1-Thioalkyl Glycoside Donors by Reaction of Per-O-acetylated Sugars with Sodium Alkanethiolates under Solvent-Free Conditions

A relatively green method for synthesizing 1-thioalkyl glycosides has been developed, where sodium alkanethiolates were used to react with per-O-acetylated sugars instead of odorous alkyl mercaptans in the presence of BF3·Et2O without the use of solvents under mild conditions. Furthermore, we found that 1,2-trans-β-thioglycosides can be converted into corresponding 1,2-cis-α-thioglycosides in the presence of trifluoromethanesulfonic acid in nonpolar solvents under mild conditions. This provides a simple and efficient new approach for synthesizing challenging 1,2-cis-α-thioglycosides.

A concise synthesis of rhamnan oligosaccharides with alternating α-(1→2)/(1→3)-linkages and repeating α-(1→3)-linkages by iterative α-glycosylation using disaccharide building blocks

A concise synthetic route to rhamnan oligosaccharides with alternating α-(1→2)/(1→3)-linkages and repeating α-(1→3)-linkages is reported. This synthesis was achieved by iterative α-glycosylation using disaccharide building blocks and through orthogonal co

Using biological performance similarity to inform disaccharide library design

Designing better small-molecule discovery libraries requires having methods to assess the consequences of different synthesis decisions on the biological performance of resulting library members. Since we are particularly interested in how stereochemistry