1812-51-7Relevant academic research and scientific papers
Palladium-catalyzed arylation of simple arenes with iodonium salts
Storr, Thomas E.,Greaney, Michael F.
supporting information, p. 1410 - 1413 (2013/05/09)
The development of an arylation protocol for simple arenes with diaryliodonium salts using the Herrmann-Beller palladacycle catalyst is reported. The reaction takes simple aromatic feedstocks and creates valuable biaryls for use in all sectors of the chem
METAL COMPLEX-CATALYZED SYNTHESIS OF DIHYDROTHIAPYRANS FROM DIALKYL SULFOXIDES AND 1,3-DIENES
Dzhemilev, U. M.,Kunakova, R. V.,Baibulatova, N. Z.,Tarasenko, A. E.,Mustafina, E. M.
, p. 128 - 134 (2007/10/02)
A preparative method has been developed for the synthesis of dihydrothiapyrans from dialkyl sulfoxides and 1,3-dienes, catalyzed by palladium and nickel complexes.The scope of this reaction has been assessed, and a mechanism proposed, using 1,3-dienes and sulfoxides of varying structure. Keywords: synthesis, dihydrothiapyrans, catalysts, mechanism, sulfides, 1,3-dienes.
