18147-56-3

Upstream product

• 13465-77-5 hexachlorodisilane 
• 10038-98-9 germaniumtetrachloride 
• 563-47-3 3-Chloro-2-methylpropene 
• 107-39-1 2,4,4-trimethyl-1-pentene 
• 10025-78-2 trichlorosilane 

Downstream Products

• 18292-38-1 2-methallyltrimethylsilane 
• 18147-84-7 2-(chloromethyl)-3-(trichlorosilyl)propene 
• 124494-13-9 1-Methoxy-4-(3-methyl-1-phenyl-but-3-enyl)-benzene 
• 6838-86-4 neophyltrichlorosilane 
• 115413-92-8 5-methyl-1-phenyl-5-hexen-3-ol 
• 23092-23-1 (+)-(R)-3-methyl-1-phenyl-3-buten-1-ol 
• 23092-23-1 (-)-(S)-3-methyl-1-phenyl-3-buten-1-ol 
• 96694-03-0 (E)-3-Hydroxy-5-methyl-1-phenyl-1,5-hexadiene 
• 151453-09-7 3-methyl-1-(4'-methoxyphenyl)-3-buten-1-ol 

Relevant academic research and scientific papers

Reactions of Tetrachlorogermane with Allyl Chloride and Methallyl Chloride in the Presence of Hexachlorodisilane as an Initiator

Allyl chloride and methallyl chloride react with tetrachlorogermane in the presence of hexachlorodisilane to give as major products allyltrichlorogermane and allyltrichlorosilane in the former case and (2-methyl-2-propenyl)trichlorogermane and (2-methyl-2-propenyl)trichlorosilane in the latter case. The reaction schemes are proposed and discussed.

Reaction of Hexachlorodisilane with Methallyl Chloride in the Gas Phase. Syntheses of Trichloro(2-niethyl-2-propenyl)silane

Reaction of methallyl chloride with hexachlorodisilane in the gas phase at 520°C was studied. Trichloro(2-methyl-2-propenyl)silane was shown to be the main reaction product. Among side products of the reaction, (cis-2-butenyl)trichlorosilane, heterocyclic, and aromatic organosilicon compounds were found. A mechanism of the reaction between hexachlorodisilane and methallyl chloride is proposed. It was shown that dichlorosilylenes generated from hexachlorodisilane prefer to react with methallyl chloride which has two reaction centers (C-Cl and C=C) at the C-Cl bond.