18167-91-4

Basic information

• Product Name: 2-(2-Methoxyphenoxy)acetaldehyde
• Synonyms: 2-(2-Methoxyphenoxy)acetaldehyde;(o-Methoxyphenoxy)acetaldehyde;Guaiacoxyacetaldehyde;O-(2-Oxoethyl)guaiacol;(2-Methoxyphenoxy)acetaldehyde
• CAS NO: 18167-91-4
• Molecular Formula: C₉H₁₀O₃
• Molecular Weight: 166
• Product Categories: Aromatics;Miscellaneous Reagents
• Mol File: 18167-91-4.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• Storage Temp.: Hygroscopic, Refrigerator, Under inert atmosphere
• Solubility: Chloroform (Soluble), Methanol (Slightly)
• Stability: Hygroscopic
• CAS DataBase Reference: 2-(2-Methoxyphenoxy)acetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-Methoxyphenoxy)acetaldehyde(18167-91-4)
• EPA Substance Registry System: 2-(2-Methoxyphenoxy)acetaldehyde(18167-91-4)

Safety Data

• Hazardous Substances Data: 18167-91-4(Hazardous Substances Data)

Usage

Chemical Properties

Off-White Solid

Uses

2-(2-Methoxyphenoxy)acetaldehyde (cas# 18167-91-4) is a compound useful in organic synthesis.

Upstream product

• 161364-38-1 2-(2-methoxyphenoxy)acetaldehyde diethyl acetal 
• 1189197-77-0 threo-1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)-1,3-propanediol 
• 7572-98-7 erythro-2-(2-Methoxyphenoxy)-1-(3,4-dimethoxyphenyl)-1,3-propan-diol 
• 93-14-1 guaifenesin 
• 10535-17-8 1-(3,4-dimethoxyphenyl)-2-(methoxyphenoxy)propane-1,3-diol 
• 4125-43-3 O-allyl guaiacol 
• 90-05-1 2-methoxy-phenol 

Downstream Products

• 103181-68-6 2-(2-methoxy-phenoxymethyl)-1,3-thiazolidine 
• 93758-01-1 (2-methoxyphenoxy)methyl vinyl ketone 
• 98689-10-2 9-Hydroxy-9-(2-methoxy-phenoxymethyl)-3-oxa-6-aza-tricyclo[6.3.1.0^1,5]dodecane-2,12-dione 
• 98689-09-9 9-Hydroxy-9-(2-methoxy-phenoxymethyl)-2,12-dioxo-3-oxa-6-aza-tricyclo[6.3.1.0^1,5]dodecane-6-carboxylic acid benzyl ester 
• 122853-43-4 2-(2-methoxyphenoxy)-ethyl methanesulphonate 
• 77164-20-6 (2S)-1-(isopropylamino)-3-(2-methoxyphenoxy)propan-2-ol 
• 1415419-09-8 (S)-1-(2-methoxyphenoxy)-3-nitropropan-2-ol 
• 371196-20-2 N-[2-(2-methoxyphenoxyl)]ethylnorthaliporphine 
• 65401-66-3 1-(2-Methoxy-phenoxy)-ethane-1,2-disulfonic acid dimethyl ester 
• 98689-08-8 3-hydroxy-4-(2-methoxyphenoxy)but-1-ene 

Relevant articles and documents

GC–MS study of thermochemical conversion of guaifenesin in the presence of 1-butyl-3-methylimidazolium-based ionic liquids

Thermochemical conversion of guaifenesin was performed in the presence of 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF4] ionic liquid at 80?°C within 2?h. After evaluating the effect of different parameters, such as protic and nonpro

Ruthenium-Catalyzed C-C bond cleavage in lignin model substrates

Ruthenium-triphos complexes exhibited unprecedented catalytic activity and selectivity in the redox-neutral C-C bond cleavage of the β-O-4 lignin linkage of 1,3-dilignol model compounds. A mechanistic pathway involving a dehydrogenation-initiated retro-aldol reaction for the C-C bond cleavage was proposed in line with experimental data and DFT calculations.

A new catalyst for the asymmetric Henry reaction: Synthesis of β-nitroethanols in high enantiomeric excess

A new chiral tetrahydrosalen ligand has been designed and synthesized from cis-2,5-diaminobicyclo[2.2.2]octane. The complex generated in situ by the interaction of the ligand with (CuOTf)2·C6H 5CH3 was an efficient catalyst for the asymmetric Henry reaction, producing nitroaldol products in high yield and good stereoselectivity. Henry reactions catalyzed by this tetrahydrosalen-Cu(I) complex led to syntheses of β-adrenergic blocking agents (S)-toliprolol, (S)-moprolol, and (S)-propanolol.