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181705-93-1

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181705-93-1 Usage

Description

4-Fluorophenylzinc bromide, also known as 4-fluorophenylzinc(II) bromide, is an organozinc compound with the chemical formula C6H5BrFZn. It is a colorless to yellow liquid with a molecular weight of 216.17 g/mol. 4-FLUOROPHENYLZINC BROMIDE is characterized by its reactivity with air and moisture, necessitating handling and storage under an inert atmosphere.

Uses

Used in Organic Synthesis:
4-Fluorophenylzinc bromide is used as a reagent in organic synthesis for forming carbon-carbon bonds through cross-coupling reactions. Its application is particularly valuable in processes such as the Suzuki-Miyaura coupling and Negishi coupling, which are widely utilized in the creation of complex organic molecules.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 4-fluorophenylzinc bromide serves as a valuable intermediate. Its role in the synthesis of various pharmaceutical compounds makes it instrumental in the development of new drugs and medicinal agents.
Used in Agrochemical Industry:
Similarly, in the agrochemical industry, 4-fluorophenylzinc bromide is utilized as an intermediate in the synthesis of various agrochemicals, contributing to the development of pesticides, herbicides, and other agricultural chemicals.
Used in Chemical Research and Development:
4-Fluorophenylzinc bromide is also used in the synthesis of various materials in chemical research and development. Its versatility in forming carbon-carbon bonds makes it a key component in the advancement of new materials and chemical processes.

Check Digit Verification of cas no

The CAS Registry Mumber 181705-93-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,1,7,0 and 5 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 181705-93:
(8*1)+(7*8)+(6*1)+(5*7)+(4*0)+(3*5)+(2*9)+(1*3)=141
141 % 10 = 1
So 181705-93-1 is a valid CAS Registry Number.
InChI:InChI=1/C6H4F.BrH.Zn/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q-1;;+2/p-1/rC6H4F.BrZn/c7-6-4-2-1-3-5-6;1-2/h2-5H;/q-1;+1

181705-93-1 Well-known Company Product Price

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  • Alfa Aesar

  • (H58780)  4-Fluorophenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles   

  • 181705-93-1

  • 50ml

  • 2278.0CNY

  • Detail
  • Aldrich

  • (498645)  4-Fluorophenylzincbromidesolution  0.5 M in THF

  • 181705-93-1

  • 498645-50ML

  • 2,356.38CNY

  • Detail

181705-93-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-FLUOROPHENYLZINC BROMIDE

1.2 Other means of identification

Product number -
Other names 4-fluorophenyl zinc bromide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:181705-93-1 SDS

181705-93-1Relevant articles and documents

Control of the dual emission from a thermally activated delayed fluorescence emitter containing phenothiazine units in organic light-emitting diodes

Marghad, Ikbal,Bencheikh, Fatima,Wang, Chao,Manolikakes, Sophia,Rérat, Alice,Gosmini, Corinne,Kim, Dae Hyeon,Ribierre, Jean-Charles,Adachi, Chihaya

, p. 4336 - 4343 (2019)

The development of single-component organic dual light-emitting molecules is of interest for a range of applications including white organic light-emitting diodes. Herein, a new thermally-activated delayed fluorescent molecule containing 4,6-bis-phenyl ph

Synthesis of Symmetrical Diaryl Ketones by Cobalt-Catalyzed Reaction of Arylzinc Reagents with Ethyl Chloroformate

Rérat, Alice,Michon, Christophe,Agbossou-Niedercorn, Francine,Gosmini, Corinne

, p. 4554 - 4560 (2016/09/23)

Symmetrical diaryl ketones were prepared by a cross-coupling reaction between aryl bromides and ethyl chloroformate. This new method, which uses a catalyst composed of CoBr2and a bipyridine ligand along with readily available starting materials, allows for the synthesis of a variety of symmetrical diaryl ketones in moderate to excellent yields (37–99 %) under mild conditions. This reaction, in which ethyl chloroformate acts as a surrogate of carbon monoxide in the presence of cobalt and zinc, represents an interesting alternative to previously known approaches for the synthesis of diarylmethanones.

CuI catalyzed sulfonylation of organozinc reagents with sulfonyl halides

Fu, Ying,Zhu, Wenbo,Zhao, Xingling,Huegel, Helmut,Wu, Zhouqiang,Su, Yuhu,Du, Zhengyin,Huang, Danfeng,Hu, Yulai

supporting information, p. 4295 - 4299 (2014/06/23)

In this study, a facile CuI catalyzed synthesis of sulfones involving a nucleophilic addition of functionalized organozinc reagents to organic sulfonyl chlorides is realized. This reaction proceeds efficiently at room temperature, giving rise to various functional group substituted sulfones, generally in moderate to high yields. The method provides a novel, simple, and promising strategy for functionalized sulfone synthesis in the research field of sulfur chemistry. the Partner Organisations 2014.

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