18231-08-8

Basic information

• Product Name: Cyclohexane, (dimethoxymethyl)-
• CAS NO: 18231-08-8
• Molecular Formula: C9H18O2
• Molecular Weight: 158.241
• Mol File: 18231-08-8.mol
• Article Data: 40

Chemical Properties

• CAS DataBase Reference: Cyclohexane, (dimethoxymethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, (dimethoxymethyl)-(18231-08-8)
• EPA Substance Registry System: Cyclohexane, (dimethoxymethyl)-(18231-08-8)

Safety Data

• Hazardous Substances Data: 18231-08-8(Hazardous Substances Data)

Upstream product

• 2043-61-0 cyclohexanecarbaldehyde 
• 108-85-0 1-bromocyclohexane 
• 149-73-5 trimethyl orthoformate 
• 67-56-1 methanol 
• 110-83-8 cyclohexene 
• 431-47-0 trifluoroacetic acid-methyl ester 
• 124-41-4 sodium methylate 
• 201230-82-2 carbon monoxide 
• 1192-88-7 1-cyclohexene-1-carboxaldehyde 
• 134986-38-2 (1R,2R)-1-Iodo-2-methoxy-cycloheptane 
• 628-92-2 Cycloheptene 
• 87705-33-7 trans-1-hydroxy-2-phenyltellurocyclohexane 
• 87705-33-7 1-Methoxy-2-phenyltellanyl-cycloheptane 
• 73090-29-6 trans-1-methoxy-2-phenylselenocycloheptane 

Downstream Products

• 63523-42-2 Cyclohexanecarbothioic acid (cyclohexyl-methoxy-methyl)-amide 
• 137250-35-2 (1-Methoxy-2-methylene-but-3-enyl)-cyclohexane 
• 137250-84-1 ((Z)-2-Chloromethyl-buta-1,3-dienyl)-cyclohexane 
• 107053-35-0 2-cyclohexyl-1,3-dioxolan-4-one 
• 54905-14-5 cyclohexane carboxaldehyde dithiophenylacetal 
• 113138-64-0 cyclohexane 
• 56698-00-1 2-cyclohexyl-1,3-dithiane 
• 144729-92-0 (3-Cyclopropyl-1-methoxy-but-3-enyl)-cyclohexane 
• 106-70-7 methyl hexanoate 
• 142836-47-3 1-chlorocyclohexanecarboxaldehyde dimethyl acetal 
• 90675-94-8 α-bromocyclohexanecarboxaldehyde dimethylacetal 
• 59039-25-7 methyl-α-chlorocyclohexylmethyl ether 
• 2948-44-9 1-methoxy-4-(1-methylcyclohexyl)benzene 
• 616-38-6 carbonic acid dimethyl ester 

Relevant articles and documents

MOF-808 as a recyclable catalyst for the photothermal acetalization of aromatic aldehydes

Metal-organic frameworks (MOFs) show promise for catalysis applications due to their porosity, high internal surface area, and structural adaptability. Typical acetylation reactions of aldehydes require elevated temperatures and excess alcohol to drive the reactions to completion. In this current work, MOF-808 is used as a heterogeneous catalyst for acetylation of aldehydes in methanol using a mild photothermal process. Optimized conditions gave 72% yield of 2-(dimethoxymethyl)naphthalene in the presence of 10 mol% MOF-808 at 45 °C using only a fluorescent lamp. MOF-808 can be recycled up to 5 times with no loss in catalytic activity. A proof-of-principle substrate scope demonstrates the potential utility for aromatic and aliphatic substrates.

Photo-organocatalytic synthesis of acetals from aldehydes

A mild and green photo-organocatalytic protocol for the highly efficient acetalization of aldehydes has been developed. Utilizing thioxanthenone as the photocatalyst and inexpensive household lamps as the light source, a variety of aromatic and aliphatic aldehydes have been converted into acyclic and cyclic acetals in high yields. The reaction mechanism was extensively studied.

Formation of Acetals and Ketals from Carbonyl Compounds: A New and Highly Efficient Method Inspired by Cationic Palladium

The development of a new, highly efficient, and simple method for masking carbonyl groups as acetals and ketals is described. This methodology relies on the nature of the palladium catalyst to direct the acetalization/ketalization reaction. This new protocol is mild and proceed with a very low catalyst loading at ambient temperatures. The method has been extended to a wide variety of different carbonyl compounds with various steric encumbrances to form the corresponding acetals and ketals in excellent yields.