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18264-71-6

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  • 3-[8,13-bis[1-(2-hydroxyethoxy)ethyl]-18-(3-methoxy-3-oxopropyl)-3,7,12,17-tetramethyl-22,23-dihydroporphyrin-2-yl]propanoic acid methyl ester

    Cas No: 18264-71-6

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  • 10 Milligram

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18264-71-6 Usage

General Description

2,2'-Dinitrodiphenylamine is a chemical compound with the molecular formula C12H10N2O4. It is a yellow crystalline solid with a slightly bitter taste, and it is commonly used as a stabilizer in the production of explosives, propellants, and rocket fuels. 2,2'-Dinitrodiphenylamine is also used as an intermediate in the synthesis of dyes, pharmaceuticals, and other organic compounds. It is considered to be toxic if ingested, inhaled, or absorbed through the skin, and prolonged exposure may cause adverse health effects. Due to its potential hazards, proper safety measures and protective equipment are required when handling this chemical.

Check Digit Verification of cas no

The CAS Registry Mumber 18264-71-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,2,6 and 4 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 18264-71:
(7*1)+(6*8)+(5*2)+(4*6)+(3*4)+(2*7)+(1*1)=116
116 % 10 = 6
So 18264-71-6 is a valid CAS Registry Number.
InChI:InChI=1/C12H9N3O4/c16-14(17)11-7-3-1-5-9(11)13-10-6-2-4-8-12(10)15(18)19/h1-8,13H

18264-71-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,2'-Dinitrodiphenylamine

1.2 Other means of identification

Product number -
Other names 2.2'-Dinitro-diphenylamin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:18264-71-6 SDS

18264-71-6Relevant articles and documents

Catalytic dioxygen activation by Co(ii) complexes employing a coordinatively versatile ligand scaffold

Sharma, Savita K.,May, Philip S.,Jones, Matthew B.,Lense, Sheri,Hardcastle, Kenneth I.,MacBeth, Cora E.

, p. 1827 - 1829 (2011)

The ligand bis(2-isobutyrylamidophenyl)amine has been prepared and used to stabilize both mononuclear and dinuclear cobalt(ii) complexes. The nuclearity of the cobalt product is regulated by the deprotonation state of the ligand. Both complexes catalytica

A terphenyl phosphine as a highly efficient ligand for palladium-catalysed amination of aryl halides with 1° anilines

Shi, Ji-cheng,Zhang, Lixue,Zhou, Fabin

, p. 238 - 243 (2021/09/07)

A terphenyl phosphine ligand (2,6-bis(2,4,6-triisopropylphenyl)phenyl-dicyclohexylphosphine, TXPhos) and its supported palladium complex [(TXPhos)(allyl)PdCl] have been developed and the catalyst system is highly efficient in amination of aryl halides with 1° anilines, especially effective for densely functionalized substrates including both partners possessing ortho-ester, acetyl, nitrile and nitro groups. With the TXPhos-supported catalyst system, many partner combinations have been unprecedentedly realized and the base scope has been even extended to KOAc, which is even the best choice in the amination of 2-nitrochlorobenzene.

Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States

Garcia-Bosch, Isaac,Lancaster, Kyle M.,Macmillan, Samantha N.,Rajabimoghadam, Khashayar,Siegler, Maxime A.,Wu, Tong

supporting information, p. 12265 - 12276 (2020/08/06)

Structural, spectroscopic, and reactivity studies are presented for an electron transfer series of copper hydroxide complexes supported by a tridentate redox-active ligand. Single crystal X-ray crystallography shows that the mononuclear [CuOH]1+ core is stabilized via intramolecular H-bonds between the H-donors of the ligand and the hydroxide anion when the ligand is in its trianionic form. This complex undergoes two reversible oxidation processes that produce two metastable "high-valent"CuOH species, which can be generated by addition of stoichiometric amounts of 1e- oxidants. These CuOH species are characterized by an array of spectroscopic techniques including UV-vis absorption, electron paramagnetic resonance (EPR), and X-ray absorption spectroscopies (XAS), which together indicate that all redox couples are ligand-localized. The reactivity of the complexes in their higher oxidation states toward substrates with modest O-H bond dissociation energies (e.g., 4-substitued-2,6-di-tert-butylphenols) indicates that these complexes act as 2H+/2e- oxidants, differing from the 1H+/1e- reactivity of well-studied [CuOH]2+ systems.

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