18290-79-4Relevant academic research and scientific papers
Hydrosilylation of cyclohexene, 1-methylcyclohexene, and isopropylidenecyclohexane
Yarosh,Zhilitskaya,Yarosh,Albanov,Voronkov
, p. 1895 - 1899 (2004)
Hydrosilylation of cyclohexene and isopropylidenecyclohexane with chloro(methyl)silanes Me3-n SiHCln (n = 1-3) gives rise to cyclohexyl- and chloro(2-cyclohexylpropyl)methylsilanes. Hydrosilylation of 1-methylcyclohexene with chlorodimethylsilane (n = 1) occurs anomalously and involves double-bond migration to form a mixture of seven compounds: the cis and trans isomers of 2-, 3-, 4-chlorodimethyl(methylcyclohexyl)silanes and chlorodimethyl(cyclohexylmethyl)silane. Chlorodimethylsilane (n = 2) adds to 1-methylcyclohexene to form a mixture of the cis and trans isomers of dichloro(methyl)(2-methylcyclohexyl)silane and dichloro(cyclohexylmethyl) methylsilane. With trichlorosilane (n = 3), no other products than trichloro(cyclohexylmethyl)silane are formed. The hydrosilylation products were reacted with ethynylmagnesium bromide to synthesize the corresponding ethynyl derivatives. 2004 MAIK "Nauka/Interperiodica".
Aluminum chloride catalyzed hydrosilylation of cyclopropanes with chlorodimethylsilane
Nagahara, Shigeru,Yamakawa, Takashi,Yamamoto, Hisashi
, p. 5057 - 5060 (2007/10/03)
Aluminum chloride can be utilized as an active catalyst for the highly regioselective hydrosilylation of 1-alkyl, 1-aryl, 1,1-dialkyl, and cyclic cyclopropanes with chlorodimethylsilane in hexane at room temperature.
