18293-51-1 Usage
Uses
Used in Pharmaceutical Industry:
(trimethylsilyl)methyl thiocyanate is used as a reagent for the synthesis of various pharmaceutical compounds. Its powerful nucleophilic nature allows for the creation of new molecules with potential therapeutic applications, contributing to the development of novel drugs and treatments.
Used in Agricultural Industry:
In the agricultural sector, (trimethylsilyl)methyl thiocyanate is utilized as a reagent in the production of insecticides and herbicides. Its involvement in the synthesis of these compounds helps in the development of more effective and targeted pest control solutions, ultimately benefiting crop protection and yield.
Used in Organic Synthesis:
(trimethylsilyl)methyl thiocyanate is employed as a nucleophilic reagent in organic synthesis, enabling the formation of new chemical bonds and the creation of a wide range of organic compounds. Its versatility in this application makes it a valuable asset in the field of chemistry, facilitating the development of new materials and substances with various potential uses.
Used in Research and Development:
(trimethylsilyl)methyl thiocyanate is also used in research and development settings, where its unique properties and reactivity are harnessed to explore new chemical reactions and investigate the potential of novel compounds. This application contributes to the advancement of scientific knowledge and the discovery of innovative solutions in various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 18293-51-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,2,9 and 3 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 18293-51:
(7*1)+(6*8)+(5*2)+(4*9)+(3*3)+(2*5)+(1*1)=121
121 % 10 = 1
So 18293-51-1 is a valid CAS Registry Number.
InChI:InChI=1/C5H11NSSi/c1-8(2,3)5-7-4-6/h5H2,1-3H3
18293-51-1Relevant academic research and scientific papers
Eosin-Mediated Alkylsulfonyl Cyanation of Olefins
Pirenne, Vincent,Kurtay, Gülbin,Voci, Silvia,Bouffier, Laurent,Sojic, Neso,Robert, Frédéric,Bassani, Dario M.,Landais, Yannick
supporting information, p. 4521 - 4525 (2018/08/09)
Eosin-Y (EY)-mediated alkylsulfonyl cyanation of olefins was shown to afford alkylsulfonyl nitriles in good yields. On the basis of transient absorption spectroscopy, the reaction was shown to proceed via photoinduced electron transfer from 3EY? to an O-cyanated derivative of the photocatalyst, formed in situ, with generation of the corresponding sulfinate that is oxidized by EY?.+ into a sulfonyl radical. Addition of the latter on the olefin, followed by a radical cyano group transfer, then furnished the nitrile along with a RSO2 radical sustaining the radical chain.
Free-Radical Carbocyanation of Olefins
Hassan, Haitham,Pirenne, Vincent,Wissing, Maren,Khiar, Chahinaz,Hussain, Ashique,Robert, Frédéric,Landais, Yannick
supporting information, p. 4651 - 4658 (2017/04/13)
The free-radical three-component carbocyanation of electron-rich olefins was investigated with p-tosyl cyanide as cyanide source. The scope and limitations of the process were established by varying the nature of the alkene and radical precursor. Carbocyanation of chiral allylsilanes was shown to occur with high diastereocontrol, leading to syn β-silyl nitriles. The origin of the stereocontrol was rationalized by a Felkin–Anh-type transition-state model. Finally, a tin-free carbocyanation process was also devised, based on the use of a new alkylsulfonyl cyanide incorporating both carbon fragments to be added across the olefinic π system.
