18293-51-1 Usage
General Description
(trimethylsilyl)methyl thiocyanate is a chemical compound with the formula C4H9NSiS. It is a colorless liquid with a garlic-like odor, and it is commonly used as a reagent in organic synthesis. (trimethylsilyl)methyl thiocyanate is typically used in the preparation of various organic compounds, such as pharmaceuticals, insecticides, and herbicides. It is also known for its ability to act as a powerful nucleophile, making it a useful tool in organic chemical reactions. Additionally, (trimethylsilyl)methyl thiocyanate is considered to be a highly reactive compound, and it should be handled with care and in accordance with proper safety protocols due to its potential hazards.
Check Digit Verification of cas no
The CAS Registry Mumber 18293-51-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,2,9 and 3 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 18293-51:
(7*1)+(6*8)+(5*2)+(4*9)+(3*3)+(2*5)+(1*1)=121
121 % 10 = 1
So 18293-51-1 is a valid CAS Registry Number.
InChI:InChI=1/C5H11NSSi/c1-8(2,3)5-7-4-6/h5H2,1-3H3
18293-51-1Relevant articles and documents
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Cooper
, p. 2499 (1954)
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Free-Radical Carbocyanation of Olefins
Hassan, Haitham,Pirenne, Vincent,Wissing, Maren,Khiar, Chahinaz,Hussain, Ashique,Robert, Frédéric,Landais, Yannick
supporting information, p. 4651 - 4658 (2017/04/13)
The free-radical three-component carbocyanation of electron-rich olefins was investigated with p-tosyl cyanide as cyanide source. The scope and limitations of the process were established by varying the nature of the alkene and radical precursor. Carbocyanation of chiral allylsilanes was shown to occur with high diastereocontrol, leading to syn β-silyl nitriles. The origin of the stereocontrol was rationalized by a Felkin–Anh-type transition-state model. Finally, a tin-free carbocyanation process was also devised, based on the use of a new alkylsulfonyl cyanide incorporating both carbon fragments to be added across the olefinic π system.
