18383-34-1Relevant articles and documents
REACTIONS OF p-TOLUENESULFONIC ACID TERPENE DERIVATIVES WITH LITHIUM IN ETHYLAMINE
Rykowski, Zbigniew,Gubrynowicz, Olaf,Wrzesien, Justyna
, p. 1237 - 1244 (2007/10/02)
Reactions of terpene p-toluenesulfonamides and p-toluenesulfonates with lithium in ethylamine were stated to afford, exclusively or mainly, respective amines and alcohols as the result of N-S or O-S bond cleavage.Presence of hydroxyl groups is not a hindrance. 2α-Hydroxy-3α-tosyloxypinane undergoes, partially, a rearrangement.The mechanism of that reaction is discussed.