18407-48-2

Usage

Uses

Used in Silicone Polymers and Resins Production:
Silane, methoxymethyldiphenylis used as a coupling agent for improving the bond between inorganic materials and organic polymers in the production of silicone polymers and resins. Its ability to react with hydroxyl groups on surfaces such as glass, metal, or ceramics forms a strong chemical bond, enhancing the performance of the silicone material.
Used in Coating Industry:
In the coating industry, Silane, methoxymethyldiphenylis used as an adhesion promoter for enhancing the durability and performance of silicone-based coatings. Its strong chemical bond with surfaces ensures better adhesion and improved resistance to environmental factors, such as UV radiation, moisture, and temperature fluctuations.
Used in Sealants and Adhesives Industry:
Silane, methoxymethyldiphenylis used as a performance enhancer in the formulation of silicone-based sealants and adhesives. Its ability to form a strong bond with various surfaces improves the adhesion and durability of the sealants and adhesives, making them suitable for a wide range of applications, including construction, automotive, and aerospace industries.
Used in High-Performance Silicone Products:
Silane, methoxymethyldiphenylis used as a key component in the development of high-performance silicone products for various industrial and consumer applications. Its role in improving the bond between inorganic and organic materials ensures superior performance, durability, and reliability of the silicone products, making them suitable for demanding applications in industries such as electronics, medical devices, and aerospace.

Upstream product

• 67-56-1 methanol 
• 144-79-6 chloromethyldiphenylsilane 
• 776-76-1 methyldiphenylsilane 
• 76889-05-9 1,1,3-Triphenyl-1-silacyclobutan 
• 18080-94-9 1,1-diphenylsilene 
• 3944-09-0 1,1-diphenylsilacyclobutane 
• 1172-76-5 1,2-dimethyl-1,1,2,2-tetraphenyldisilane 
• 1185-55-3 Methyltrimethoxysilan 
• 100-59-4 phenylmagnesium chloride 
• 98-95-3 nitrobenzene 
• 287978-57-8 diphenylmethylsilyl formate 
• 6843-66-9 dimethoxy(diphenyl)silane 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 6231-82-9 -methanol 
• 17739-53-6 di-phenylmethylsilyl fluoride 
• 807-28-3 1,3-Dimethyl-1,1,3,3-tetraphenyldisiloxan 
• 776-76-1 methyldiphenylsilane 
• 1450-16-4 1,1,1,2-tetramethyl-2,2-diphenyldisilane 

Relevant academic research and scientific papers

THERMOLYSE UND PHOTOLYSE EINIGER SILA- UND DISILACYCLOBUTANE

The thermolysis of some 1,1-di- or 1,1,2-tri-substituted 1-silacyclobutanes leads to 1,3-disilacyclobutanes or to polymeric products.A possible intermediate silaalkene could not be stabilized, even in the presence of bulky substituents at the silicon atom.Photolysis of some di- or tri-substituted silacyclobutanes in methanol results in ring opening or in elimination of an alkene with further reaction of the intermediates with the solvent.Photolysis of the 1,1-diphenyl-2-methyl-1-silacyclobutane in cyclohexane leads to the 1,1,3,3-tetraphenyl-1,3-disilacyclobutane.The influence of the substituents at the silicon or the carbon atom on the reaction pathways is discussed.Photolysis opening and addition of methanol, whereas the 1,1,3,3-tetraphenyl-1,3-disilacyclobutane does not show any reaction.

Highly Selective Hydroxylation and Alkoxylation of Silanes: One-Pot Silane Oxidation and Reduction of Aldehydes/Ketones

An efficient chemoselective iridium-catalyzed method for the hydroxylation and alkoxylation of organosilanes to generate hydrogen gas and silanols or silyl ethers was developed. A variety of sterically hindered silanes with alkyl, aryl, and ether groups were tolerated. Furthermore, this atom-economical catalytic protocol can be used for the synthesis of silanediols and silanetriols. A one-pot silane oxidation and chemoselective reduction of aldehydes/ketones was also realized.

Catalytic Disproportionation of Formic Acid to Methanol by using Recyclable Silylformates

A novel strategy to prepare methanol from formic acid without an external reductant is presented. The overall process described herein consists of the disproportionation of silyl formates to methoxysilanes, catalyzed by ruthenium complexes, and the production of methanol by simple hydrolysis. Aqueous solutions of MeOH (>1 mL, >70 percent yield) were prepared in this manner. The sustainability of the reaction has been established by recycling of the silicon-containing by-products with inexpensive, readily available, and environmentally benign reagents.

Silica-supported ultra small gold nanoparticles as nanoreactors for the etherification of silanes

Ultra small gold nanoparticles supported by porous silica (Au-SiO2) were successfully synthesized. Due to enrichment of reactants by silica, the Au-SiO2 particles functioned as nanoreactors for catalytic etherification of silanes wit

Synthesis of phenyl-methyl dialkoxy silane method of the

The invention relates to a method for synthesizing phenyl methyl dialkoxyl silane with high selectivity. The structural formula of phenyl methyl dialkoxyl silane is PhMeSi(OR)2, in which R is alkyl with 1-6 carbons. The method is characterized by comprising the following steps of: performing reaction with methyl trialkoxyl silane based on non-cyclic ether compounds such as ethyl ether as a reaction liquor and a bromobenzene Grignard reagent as a raw material; and then, obtaining the target compound, i.e., phenyl methyl dialkoxyl silane with high selectivity and high yield through simple filtering and fractional purification, and meanwhile, greatly inhibiting the generation of a byproduct diphenyl methyl alkoxyl silane.

Meerwein's reagent mediated, significantly enhanced nucleophilic fluorination on alkoxysilanes

We developed a new facile method to fluorosilanes from alkoxysilanes using Meerwein's reagent. Our protocol afforded fluorosilanes in excellent yields in various organic solvents including acetonitrile under mild reaction conditions at room temperature. We also proposed a reaction mechanism with the probable silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.

An efficient method for the synthesis of symmetrical disiloxanes from alkoxysilanes using Meerwein's reagent

We report here a new and efficient route to symmetrical disiloxanes from their corresponding alkoxysilanes using Meerwein's reagent as mediator and potassium carbonate as additive under mild reaction conditions in acetonitrile. Our methodology is very simple, economic, and high yielding. We have also proposed a reaction mechanism with the plausible silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.

Gold nanoparticles-catalyzed activation of 1,2-disilanes: Hydrolysis, silyl protection of alcohols and reduction of tert-benzylic alcohols

Gold nanoparticles supported on TiO2 catalyze under mild conditions the activation of a series of 1,2-disilanes towards hydrolysis and alcoholysis, with concomitant evolution of H2 gas. For the case of tert-benzyl alcohols, the main or only pathway is reduction to the corresponding alkanes.

An efficient solvent-free route to silyl esters and silyl ethers

Dinuclear metal complexes, especially (p-cymene)ruthenium dichloride dimer {[RuCl2(p-cymene)]2}, have been found to exhibit high catalytic performance for the dehydrosilylation of various kinds of carboxylic acids and alcohols. The dehydrosilylation with [RuCl2(p-cymene)] 2 proceeded efficiently with only one equivalent of silane with respect to substrate (carboxylic acids or alcohols) under solvent-free conditions to give the corresponding silyl esters and ethers in excellent yields with a high turnover number (TON) and frequency (TOF). The 1H NMR spectrum of a toluene-d8 solution of [RuCl2(p-cymene)] 2 and a silane showed a signal assignable to the ruthenium hydride species. In contrast, no new signals were detected in the 1H NMR spectrum of a toluene-d8 solution of [RuCl2(p-cymene)] 2 and a carboxylic acid or an alcohol. There-fore, the ruthenium metal in [RuCl2(p-cymene)]2 activates a silane to afford the hydride intermediate, possibly a silylmetal hydride species. Then, the nucleophilic attack of a substrate (carboxylic acid or alcohol) to the hydride intermediate proceeds to give the corresponding silylated product. The present dehydrosilylation with an optically active silane proceeded exclusively under inversion of stereochemistry at the chiral silicon center, suggesting that the nucleophilic attack of a substrate to the hydride intermediate occurs from the backside of the ruthenium-silicon bond.

Organogermanium reactive intermediates. The direct detection and characterization of transient germylenes and digermenes in solution

Diphenylgermylene (Ph2Ge) and its Ge=Ge doubly bonded dimer, tetraphenyldigermene (6a), have been characterized directly in solution for the first time by laser flash photolysis methods. The germylene is formed via (formal) cheletropic photocycloreversion of 3,4-dimethyl-1,1- diphenylgermacyclopent-3-ene (4a), which is shown to proceed in high chemical (>95%) and quantum yield (Φ = 0.62) by steady-state trapping experiments with methanol, acetic acid, isoprene, and triethylsilane. Flash photolysis of 4a in dry deoxygenated hexane at 23°C leads to the prompt formation of a transient assigned to Ph2Ge (∈max = 500 nm; ∈max = 1650 M-1 cm-1), which decays with second-order kinetics (τ ≈ 3 μs), with the concomitant growth of a second transient species that is assigned to digermene 6a (τ ≈ 40 μs; λmax = 440 nm). Analogous results are obtained from 1,1-dimesityl- and 1,1-dimethyl-3,4-dimethylgermacyclopent-3-ene (4b and 4c, respectively), which afford Mes2Ge (τ = 20 μs; λmax = 560 nm) and Me2Ge (τ ≈ 2 μs; λs; λmax = 480 nm), respectively, as well as the corresponding digermenes, tetramesityl- (6b; λmax = 410 nm) and tetramethyldigermene (6c; λmax = 370 nm). The results for the mesityl compound are compared to the analogous ones from laser flash photolysis of the known Mes2Ge/6b precursor, hexamesitylcyclotrigermane. The spectra of the three germylenes and two of the digermenes are in excellent agreement with calculated spectra, derived from time-dependent DFT calculations. Absolute rate constants for dimerization of Ph2Ge and Mes2Ge and for their reaction with n-butylamine and acetic acid in hexane at 23°C are also reported.