18465-32-2

Usage

InChI:InChI=1/C6H11ClO5/c7-1-3(9)5(11)6(12)4(10)2-8/h2-6,9-12H,1H2/t3-,4+,5+,6-/m1/s1

Upstream product

• 19685-14-4 6-chloro-O¹,O²;O³,O⁵-diisopropylidene-α-D-6-deoxy-glucofuranose 
• 50-99-7 D-glucose 
• 124-63-0 methanesulfonyl chloride 
• 4990-87-8 6-chloro-tri-O-chlorosulfonyl-α-D-6-deoxy-mannopyranosyl chloride 
• 4990-84-5 methyl 6-chloro-6-deoxy-β-D-glucopyranoside 

Downstream Products

• 76986-26-0 6-chloro-6-deoxy-D-glucitol 
• 99786-29-5 6-chloro-D-arabino-6-deoxy-[2]hexosulose-bis-phenylhydrazone 

Relevant academic research and scientific papers

FACILE PREPARATION OF DEOXYIODOCELLULOSE AND ITS CONVERSION INTO 5,6-CELLULOSENE

Treatment of 6-chloro-6-deoxycellulose with sodium iodide in 2,5-hexanedione gave 6-deoxy-6-iodocellulose; > 80 percent of the chlorine atoms were replaced. 6-Deoxy-6-iodo-D-glucose was identified by g.l.c.-m.s. in hydrolyzates of deoxyiodocellulose.Acetylated 6-deoxy-6-iodocellulose was converted almost quantitatively into 5,6-cellulosene acetate, wich was characterized by hydrolyzing the product and converting the resultant dicarbonyl sugar into an isopropylidene acetal 10.The changes of molecular-weight distribution during iodination and dehydroiodination were investigated by gel-permeation chromatography.

Process for the preparation of chlorodeoxysugars

A process for the preparation of a chlorodeoxy derivative of a reducing aldose having a primary hydroxy group in an exocyclic -CH2 OH group, in which the said primary hydroxy group is replaced by a chlorine atom to give a chlorodeoxy reducing sugar with a free anomeric center, characterized in that the free reducing sugar is reacted with a reagent comprising an N,N-dialkyl (methaniminium) chloride obtained by reacting an N,N-dialkyl formamide with a chlorinating agent.