185-49-9Relevant academic research and scientific papers
Reactions of Spirohept-4-ene Derivatives with Tetracyanoethylene. Extensive Rearrangements Involving the Aza-Cope Process
Nishida, Shinya,Asanuma, Naoki,Murakami, Masashi,Tsuji, Takashi,Imai, Toshiro
, p. 4658 - 4663 (2007/10/02)
In CH2Cl2 or CH3CN, 1,1-dicyclopropylspirohept-4-ene (4a) reacted readily with TCNE in a unique manner to give 4--6-methylenebicyclooct-3-ene-2,2,3-tricarbonitrile (8a), an imine after extensive rearrangements,
DEBROMINATION OF 1,1-BIS(BROMOMETHYL)CYCLANES
Slobodin, Ya.M.
, p. 459 - 461 (2007/10/02)
It was shown that the composition of the debromination products from 1,1-bis(bromomethyl)cyclanes depends on the strain energy of the initial ring.
