185197-15-3

Basic information

• Product Name: Benzenecarboximidic acid, N-methoxy-, phenylmethyl ester, (Z)-
• CAS NO: 185197-15-3
• Molecular Formula: C15H15NO2
• Molecular Weight: 241.29
• Mol File: 185197-15-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 342.5±35.0 °C(Predicted)
• Density: 1.03±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Benzenecarboximidic acid, N-methoxy-, phenylmethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidic acid, N-methoxy-, phenylmethyl ester, (Z)-(185197-15-3)
• EPA Substance Registry System: Benzenecarboximidic acid, N-methoxy-, phenylmethyl ester, (Z)-(185197-15-3)

Safety Data

• Hazardous Substances Data: 185197-15-3(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 2446-51-7 N-methoxybenzamide 
• 100-39-0 benzyl bromide 

Downstream Products

• 701975-89-5 (Z)-2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1,2-diphenylethanone O-methyloxime 
• 530-36-9 threo-1,2-diphenyl-2-aminoethan-1-ol 
• 530-36-9 erythro-2-amino-1,2-diphenylethanol 
• 161869-75-6 (Z)-2-hydroxy-1,2-diphenylethanone O-methyloxime 

Relevant articles and documents

Imino 1,2-Wittig rearrangement of hydroximates and its application to synthesis of cytoxazone

The imino 1,2-Wittig rearrangement of hydroximates provides a novel method for the construction of 2-hydroxyoxime ethers. Upon treatment with LDA, Z-hydroximates smoothly underwent stereoselective rearrangement to give Z-2-hydroxyoxime ethers in good yield, which were converted into amino alcohols. On the other hand, the rearrangement of E-hydroximates gave a mixture of E- and Z-2-hydroxyoxime ethers. This method was successfully applied to a practical synthesis of cytoxazone.