18602-95-4

Basic information

• Product Name: Silane, iodotriphenyl-
• CAS NO: 18602-95-4
• Molecular Formula: C18H15ISi
• Molecular Weight: 386.307
• Mol File: 18602-95-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, iodotriphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, iodotriphenyl-(18602-95-4)
• EPA Substance Registry System: Silane, iodotriphenyl-(18602-95-4)

Safety Data

• Hazardous Substances Data: 18602-95-4(Hazardous Substances Data)

Upstream product

• 56-23-5 tetrachloromethane 
• 7553-56-2 iodine 
• 789-25-3 HSiPh₃ 
• 67-66-3 chloroform 
• 141272-70-0 3(C₄H₈O)*LiSi(C₆H₅)3=(C₄H₈O)3LiSi(C₆H₅)3 
• 775-12-2 diphenylsilane 
• 80-10-4 diphenylsilyl dichloride 
• 694-53-1 phenylsilane 
• 98-13-5 Phenyltrichlorosilane 
• 76-86-8 Triphenylsilyl chloride 
• 618-38-2 benzoyl iodide 
• 791-31-1 triphenylhydroxysilane 
• 1516-80-9 ethoxytriphenylsilane 
• 507-02-8 acetyl iodide 

Relevant articles and documents

Acyl iodides in organic synthesis: X. Reactions with triorganylsilanes and triphenylgermane

Reaction of acyl iodides RCOI (R = Me, Ph) with triorganylsilanes R′2R″SiH in toluene gives 50-60% of the corresponding triorganyliodosilanes R′2R″SiI. Triethylsilane reacts with the same acyl iodides under solvent-free conditions to afford the corresponding aldehyde and triethyliodosilane as primary products. Triethyliodosilane undergoes subsequent transformations into hexaethyldisiloxane and triethyl(acyloxy)silane Et3SiOCOR (R = Me, Ph). Reactions of acyl iodides RCOI (R = Me, Ph) with triphenylgermane in the absence of a solvent lead to formation of iodo(triphenyl)germane in more than 90% yield.

Acyl iodides in organic synthesis. Reaction of acyl iodides with triphenylethoxy- and triphenylhydroxysilane

The reaction of triphenylethoxysilane with acetyl or benzoyl iodide led to the formation of triphenyliodosilane and ethyl ester of the corresponding carboxylic acid. Triphenyliodosilane formed also in the reaction of triphenylsilanol with benzoyl iodide.